Industrial & Engineering Chemistry Research, volume 61, issue 5, pages 1994-2009
Synergy of Acidity and Morphology of Micro-/Mesoporous Materials in the Solid-Acid Alkylation of Toluene with 1-Decene
Publication type: Journal Article
Publication date: 2022-01-27
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.2
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Abstract
Tuning the morphology of heterogeneous catalysts is of paramount importance for the design of efficient processes and requires detailed information on the physicochemical characteristics of the materials. Four micro-/mesoporous composites with different morphologies were synthesized by a dual-templating method using two-step crystallization with different zeolite seed concentrations. This work demonstrates the dependence of selectivity on the catalyst nature in solid-acid alkylation. It was demonstrated that a high concentration of weak acid sites leads to dialkyltoluene products, whereas a high concentration of strong acid sites is beneficial for other side reactions. It was shown that the morphology of catalysts played a crucial role in solid-acid alkylation. The alkylation mechanism defined in this study with different contributions of weak and strong acid sites could provide a route to the development of effective solid-acid catalysts.
Citations by journals
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3
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Petroleum Chemistry
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Petroleum Chemistry
3 publications, 27.27%
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Nanoscale Advances
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Nanoscale Advances
1 publication, 9.09%
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Microporous and Mesoporous Materials
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Microporous and Mesoporous Materials
1 publication, 9.09%
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Applied Catalysis B: Environmental
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Applied Catalysis B: Environmental
1 publication, 9.09%
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Catalysis Science and Technology
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Catalysis Science and Technology
1 publication, 9.09%
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Catalysts
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Catalysts
1 publication, 9.09%
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Micro
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Micro
1 publication, 9.09%
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Energy & Fuels
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Energy & Fuels
1 publication, 9.09%
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Computational Materials Science
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Computational Materials Science
1 publication, 9.09%
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1
2
3
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Citations by publishers
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1
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3
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Pleiades Publishing
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Pleiades Publishing
3 publications, 27.27%
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Elsevier
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Elsevier
3 publications, 27.27%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
2 publications, 18.18%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 18.18%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 9.09%
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1
2
3
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Sadovnikov A. A. et al. Synergy of Acidity and Morphology of Micro-/Mesoporous Materials in the Solid-Acid Alkylation of Toluene with 1-Decene // Industrial & Engineering Chemistry Research. 2022. Vol. 61. No. 5. pp. 1994-2009.
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Sadovnikov A. A., Arapova O. V., Russo V., Maximov A., Murzin D. Y., Naranov E. R. Synergy of Acidity and Morphology of Micro-/Mesoporous Materials in the Solid-Acid Alkylation of Toluene with 1-Decene // Industrial & Engineering Chemistry Research. 2022. Vol. 61. No. 5. pp. 1994-2009.
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TY - JOUR
DO - 10.1021/acs.iecr.1c04169
UR - https://doi.org/10.1021%2Facs.iecr.1c04169
TI - Synergy of Acidity and Morphology of Micro-/Mesoporous Materials in the Solid-Acid Alkylation of Toluene with 1-Decene
T2 - Industrial & Engineering Chemistry Research
AU - Arapova, Olga V
AU - Russo, Vincenzo
AU - Murzin, Dmitry Yu.
AU - Naranov, Evgeny R
AU - Sadovnikov, A. A.
AU - Maximov, Anton
PY - 2022
DA - 2022/01/27 00:00:00
PB - American Chemical Society (ACS)
SP - 1994-2009
IS - 5
VL - 61
SN - 0888-5885
SN - 1520-5045
ER -
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@article{2022_Sadovnikov,
author = {Olga V Arapova and Vincenzo Russo and Dmitry Yu. Murzin and Evgeny R Naranov and A. A. Sadovnikov and Anton Maximov},
title = {Synergy of Acidity and Morphology of Micro-/Mesoporous Materials in the Solid-Acid Alkylation of Toluene with 1-Decene},
journal = {Industrial & Engineering Chemistry Research},
year = {2022},
volume = {61},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021%2Facs.iecr.1c04169},
number = {5},
pages = {1994--2009},
doi = {10.1021/acs.iecr.1c04169}
}
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MLA
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Sadovnikov, A. A., et al. “Synergy of Acidity and Morphology of Micro-/Mesoporous Materials in the Solid-Acid Alkylation of Toluene with 1-Decene.” Industrial & Engineering Chemistry Research, vol. 61, no. 5, Jan. 2022, pp. 1994-2009. https://doi.org/10.1021%2Facs.iecr.1c04169.