Inorganic Chemistry, volume 59, issue 22, pages 16122-16126
Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution
3
Leibniz Institute of Surface Engineering (IOM), Permoserstraße 15, 04318 Leipzig, Germany
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Publication type: Journal Article
Publication date: 2020-10-26
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The fully oxidized Lindqvist-type hexavanadate compounds decorated by phosphine-derivatized Au(I) moieties oriented in a transoid fashion (n-Bu4N)2[V6O13{(OCH2)3CCH2(N3C2C6H5)AuP(C6H4OMe)3}2] (POMNAu) and (n-Bu4N)2[V6O13{(OCH2)3CCH2OCH2(C2N3H)AuP(C6H4OMe)3}2] (POMCAu) have been prepared by azide-alkyne cycloaddition reactions and characterized by various techniques, including NMR, IR, and UV/vis spectroscopy and electrospray ionization mass spectrometry. Electronic structure calculations unveil the potential of these model hybrid junctions for application in controlled charge-transport experiments on substrate surfaces.
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- We do not take into account publications that without a DOI.
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Petrovskii S. et al. Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution // Inorganic Chemistry. 2020. Vol. 59. No. 22. pp. 16122-16126.
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Petrovskii S., Khistiaeva V. V., Sizova A. A., Sizov V., Paderina A., Koshevoy I. O., Monakhov K. Y., Grachova E. V. Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution // Inorganic Chemistry. 2020. Vol. 59. No. 22. pp. 16122-16126.
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TY - JOUR
DO - 10.1021/acs.inorgchem.0c02621
UR - https://doi.org/10.1021%2Facs.inorgchem.0c02621
TI - Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution
T2 - Inorganic Chemistry
AU - Sizov, V.
AU - Paderina, Aleksandra
AU - Koshevoy, Igor O
AU - Monakhov, Kirill Yu.
AU - Grachova, Elena V
AU - Petrovskii, Stanislav
AU - Khistiaeva, Viktoria V
AU - Sizova, Anastasia A
PY - 2020
DA - 2020/10/26 00:00:00
PB - American Chemical Society (ACS)
SP - 16122-16126
IS - 22
VL - 59
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2020_Petrovskii,
author = {V. Sizov and Aleksandra Paderina and Igor O Koshevoy and Kirill Yu. Monakhov and Elena V Grachova and Stanislav Petrovskii and Viktoria V Khistiaeva and Anastasia A Sizova},
title = {Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021%2Facs.inorgchem.0c02621},
number = {22},
pages = {16122--16126},
doi = {10.1021/acs.inorgchem.0c02621}
}
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Petrovskii, Stanislav, et al. “Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution.” Inorganic Chemistry, vol. 59, no. 22, Oct. 2020, pp. 16122-16126. https://doi.org/10.1021%2Facs.inorgchem.0c02621.
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