American Chemical Society (ACS)
Inorganic Chemistry
,  volume 59 ,  issue 22 ,  pages 16122-16126

Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution

Publication type: Journal Article
Publication date: 2020-10-26
American Chemical Society (ACS)
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The fully oxidized Lindqvist-type hexavanadate compounds decorated by phosphine-derivatized Au(I) moieties oriented in a transoid fashion (n-Bu4N)2[V6O13{(OCH2)3CCH2(N3C2C6H5)AuP(C6H4OMe)3}2] (POMNAu) and (n-Bu4N)2[V6O13{(OCH2)3CCH2OCH2(C2N3H)AuP(C6H4OMe)3}2] (POMCAu) have been prepared by azide-alkyne cycloaddition reactions and characterized by various techniques, including NMR, IR, and UV/vis spectroscopy and electrospray ionization mass spectrometry. Electronic structure calculations unveil the potential of these model hybrid junctions for application in controlled charge-transport experiments on substrate surfaces.
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Petrovskii S. K. et al. Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution // Inorganic Chemistry. 2020. Vol. 59. No. 22. pp. 16122-16126.
GOST all authors (up to 50) Copy
Petrovskii S., Petrovskii S. K., Khistiaeva V. V., Sizova A. A., Sizov V., Paderina A., Koshevoy I. O., Monakhov K. Y., Grachova E. V. Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution // Inorganic Chemistry. 2020. Vol. 59. No. 22. pp. 16122-16126.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.0c02621
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02621
TI - Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution
T2 - Inorganic Chemistry
AU - Petrovskii, Stanislav
AU - Petrovskii, Stanislav K
AU - Khistiaeva, Viktoria V
AU - Sizova, Anastasia A
AU - Sizov, V.
AU - Paderina, Aleksandra
AU - Koshevoy, Igor O
AU - Monakhov, Kirill Yu.
AU - Grachova, Elena V
PY - 2020
DA - 2020/10/26
PB - American Chemical Society (ACS)
SP - 16122-16126
IS - 22
VL - 59
PMID - 33103900
SN - 0020-1669
SN - 1520-510X
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2020_Petrovskii,
author = {Stanislav Petrovskii and Stanislav K Petrovskii and Viktoria V Khistiaeva and Anastasia A Sizova and V. Sizov and Aleksandra Paderina and Igor O Koshevoy and Kirill Yu. Monakhov and Elena V Grachova},
title = {Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution},
journal = {Inorganic Chemistry},
year = {2020},
volume = {59},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02621},
number = {22},
pages = {16122--16126},
doi = {10.1021/acs.inorgchem.0c02621}
}
MLA
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MLA Copy
Petrovskii, Stanislav K., et al. “Hexavanadate–Organogold(I) Hybrid Compounds: Synthesis by the Azide–Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution.” Inorganic Chemistry, vol. 59, no. 22, Oct. 2020, pp. 16122-16126. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02621.
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