volume 60 issue 24 pages 18854-18858

Synthesis and Structural Characterization of Palladium(II) Mixed-Ligand Complexes of N-(Benzothiazol-2-yl)benzamide and 1,2-Bis(diphenylphosphino)ethane

Ahmed A Irzoqi 1
Faisal A Salman 1
Yuosra K Alasadi 1
M.I. Alheety 2
Publication typeJournal Article
Publication date2021-12-09
scimago Q1
wos Q1
SJR0.958
CiteScore7.4
Impact factor4.7
ISSN00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Three novel palladium(II) mixed-ligand complexes of N-(benzothiazol-2-yl)benzamide (HL) and 1,2-bis(diphenylphosphino)ethane (dppe), [Pd(HL)(dppe)]Cl2 (1), [Pd(L)(dppe)]Cl (2), and [Pd(L)2(dppe)] (3), were synthesized and fully characterized using Fourier transform infrared, 1H, 13C, and 31P NMR, and molar conductivity measurements. Complex 3 was characterized by single-crystal X-ray diffraction. The ligand HL showed three different coordination modes: a neutral bidentate chelate bound through the endocyclic nitrogen and exocyclic oxygen atoms in 1, a negatively charged L bound as a bidentate chelate through the endocyclic nitrogen and negatively charged exocyclic oxygen atoms in 2, and a monodentate bound through the negatively charged endocyclic nitrogen atom in 3.
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Irzoqi A. A. et al. Synthesis and Structural Characterization of Palladium(II) Mixed-Ligand Complexes of N-(Benzothiazol-2-yl)benzamide and 1,2-Bis(diphenylphosphino)ethane // Inorganic Chemistry. 2021. Vol. 60. No. 24. pp. 18854-18858.
GOST all authors (up to 50) Copy
Irzoqi A. A., Salman F. A., Alasadi Y. K., Alheety M. Synthesis and Structural Characterization of Palladium(II) Mixed-Ligand Complexes of N-(Benzothiazol-2-yl)benzamide and 1,2-Bis(diphenylphosphino)ethane // Inorganic Chemistry. 2021. Vol. 60. No. 24. pp. 18854-18858.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.1c02584
UR - https://doi.org/10.1021/acs.inorgchem.1c02584
TI - Synthesis and Structural Characterization of Palladium(II) Mixed-Ligand Complexes of N-(Benzothiazol-2-yl)benzamide and 1,2-Bis(diphenylphosphino)ethane
T2 - Inorganic Chemistry
AU - Irzoqi, Ahmed A
AU - Salman, Faisal A
AU - Alasadi, Yuosra K
AU - Alheety, M.I.
PY - 2021
DA - 2021/12/09
PB - American Chemical Society (ACS)
SP - 18854-18858
IS - 24
VL - 60
PMID - 34882387
SN - 0020-1669
SN - 1520-510X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Irzoqi,
author = {Ahmed A Irzoqi and Faisal A Salman and Yuosra K Alasadi and M.I. Alheety},
title = {Synthesis and Structural Characterization of Palladium(II) Mixed-Ligand Complexes of N-(Benzothiazol-2-yl)benzamide and 1,2-Bis(diphenylphosphino)ethane},
journal = {Inorganic Chemistry},
year = {2021},
volume = {60},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.inorgchem.1c02584},
number = {24},
pages = {18854--18858},
doi = {10.1021/acs.inorgchem.1c02584}
}
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Irzoqi, Ahmed A., et al. “Synthesis and Structural Characterization of Palladium(II) Mixed-Ligand Complexes of N-(Benzothiazol-2-yl)benzamide and 1,2-Bis(diphenylphosphino)ethane.” Inorganic Chemistry, vol. 60, no. 24, Dec. 2021, pp. 18854-18858. https://doi.org/10.1021/acs.inorgchem.1c02584.