Inorganic Chemistry, volume 61, issue 30, pages 11629-11638
So Close, Yet so Different: How One Donor Atom Changes Significantly the Photophysical Properties of Mononuclear Cu(I) Complexes
Publication type: Journal Article
Publication date: 2022-07-05
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The manipulation of the photophysical properties of molecular emitters can be realized by composing the close environment of the metal center with the "heavier pnictogen atom" effect. Replacing a nitrogen atom with a heavier phosphorus atom in otherwise isostructural molecular systems results in a significant change of the photophysical parameters. Herein, we report on the synthesis of four pairs of novel phosphinine-based and isostructural diimine-based Cu(I) complexes, which feature peculiar photophysical properties, and show how these parameters depend on the "heavier pnictogen atom" effect. The obtained Cu(I) complexes show triplet luminescence with MLCT character, which was investigated by means of spectroscopic and computational methods. It has been found that the photophysical properties of the coordination compounds show a dependency on the rigidity of the ancillary phosphine ligand in an unexpected manner. Replacing the nitrogen atom with a heavier phosphorus atom in otherwise isostructural molecular systems results in a significant change in emission energy and especially in the lifetime of the excited state. The results obtained demonstrate an efficient approach to the design of emissive molecular materials, which allows the construction of luminescent complexes with controlled photophysical properties.
Citations by journals
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Dalton Transactions
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Dalton Transactions
3 publications, 33.33%
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1 publication, 11.11%
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1 publication, 11.11%
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1 publication, 11.11%
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MolBank
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MolBank
1 publication, 11.11%
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European Journal of Inorganic Chemistry
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European Journal of Inorganic Chemistry
1 publication, 11.11%
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Citations by publishers
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4
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
4 publications, 44.44%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
2 publications, 22.22%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 11.11%
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Wiley
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Wiley
1 publication, 11.11%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Paderina A. et al. So Close, Yet so Different: How One Donor Atom Changes Significantly the Photophysical Properties of Mononuclear Cu(I) Complexes // Inorganic Chemistry. 2022. Vol. 61. No. 30. pp. 11629-11638.
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Paderina A., Ramazanov R., Valiev R. R., Müller C., Grachova E. V. So Close, Yet so Different: How One Donor Atom Changes Significantly the Photophysical Properties of Mononuclear Cu(I) Complexes // Inorganic Chemistry. 2022. Vol. 61. No. 30. pp. 11629-11638.
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TY - JOUR
DO - 10.1021/acs.inorgchem.2c01145
UR - https://doi.org/10.1021%2Facs.inorgchem.2c01145
TI - So Close, Yet so Different: How One Donor Atom Changes Significantly the Photophysical Properties of Mononuclear Cu(I) Complexes
T2 - Inorganic Chemistry
AU - Müller, Christian
AU - Paderina, Aleksandra
AU - Ramazanov, Ruslan
AU - Valiev, R. R.
AU - Grachova, Elena V
PY - 2022
DA - 2022/07/05 00:00:00
PB - American Chemical Society (ACS)
SP - 11629-11638
IS - 30
VL - 61
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2022_Paderina,
author = {Christian Müller and Aleksandra Paderina and Ruslan Ramazanov and R. R. Valiev and Elena V Grachova},
title = {So Close, Yet so Different: How One Donor Atom Changes Significantly the Photophysical Properties of Mononuclear Cu(I) Complexes},
journal = {Inorganic Chemistry},
year = {2022},
volume = {61},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021%2Facs.inorgchem.2c01145},
number = {30},
pages = {11629--11638},
doi = {10.1021/acs.inorgchem.2c01145}
}
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Paderina, Aleksandra, et al. “So Close, Yet so Different: How One Donor Atom Changes Significantly the Photophysical Properties of Mononuclear Cu(I) Complexes.” Inorganic Chemistry, vol. 61, no. 30, Jul. 2022, pp. 11629-11638. https://doi.org/10.1021%2Facs.inorgchem.2c01145.
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