Solvation Properties of Triethylammonium-Based Protic Ionic Liquids
Timur I Magsumov
1
,
Yaroslav E. Chumakov
1
,
Yurii Chumakov
1
,
Bulat R. Gainutdinov
1
,
R A Larionov
1
,
Askar K Gatiatulin
1
,
A K Gatiatulin
1
,
Ivan A Andreev
2
,
Nina K Ratmanova
2
,
Olga Ivanova
3
,
Igor V Trushkov
1, 4
,
Publication type: Journal Article
Publication date: 2024-11-29
scimago Q2
wos Q2
SJR: 0.449
CiteScore: 4.0
Impact factor: 2.1
ISSN: 00219568, 15205134
Abstract
Protic ionic liquids have numerous promising applications as solvents and are more straightforward and less expensive to synthesize than aprotic ionic liquids. This study expands the scarce knowledge on the solvation properties of protic ionic liquids by considering three triethylammonium salts: acetate, trifluoroacetate, and triflate. Additionally, they were characterized by means of TG/DSC analysis and low-temperature DSC in order to determine the liquid range temperature. The limiting activity coefficients of alkanes, alkenes, aromatic hydrocarbons, cycloalkanes, cyclohexene, and thiophene at 298.15 K were measured in these liquids. A higher solubility of hydrocarbons in triethylammonium salts than in many aprotic and several studied protic ionic liquids was observed. The selectivity of triethylammonium triflate for n-hexane/benzene separation is higher than that of sulfolane and N-methyl-2-pyrrolidinone used in industrial extraction processes.
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Total citations:
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Citations from 2024:
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(100%)
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Magsumov T. I. et al. Solvation Properties of Triethylammonium-Based Protic Ionic Liquids // Journal of Chemical & Engineering Data. 2024. Vol. 70. No. 1. pp. 359-369.
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Magsumov T. I., Chumakov Y. E., Chumakov Y., Gainutdinov B. R., Larionov R. A., Gatiatulin A. K., Gatiatulin A. K., Andreev I. A., Ratmanova N. K., Ivanova O., Trushkov I. V., Sedov I. A. Solvation Properties of Triethylammonium-Based Protic Ionic Liquids // Journal of Chemical & Engineering Data. 2024. Vol. 70. No. 1. pp. 359-369.
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TY - JOUR
DO - 10.1021/acs.jced.4c00442
UR - https://pubs.acs.org/doi/10.1021/acs.jced.4c00442
TI - Solvation Properties of Triethylammonium-Based Protic Ionic Liquids
T2 - Journal of Chemical & Engineering Data
AU - Magsumov, Timur I
AU - Chumakov, Yaroslav E.
AU - Chumakov, Yurii
AU - Gainutdinov, Bulat R.
AU - Larionov, R A
AU - Gatiatulin, Askar K
AU - Gatiatulin, A K
AU - Andreev, Ivan A
AU - Ratmanova, Nina K
AU - Ivanova, Olga
AU - Trushkov, Igor V
AU - Sedov, Igor A.
PY - 2024
DA - 2024/11/29
PB - American Chemical Society (ACS)
SP - 359-369
IS - 1
VL - 70
SN - 0021-9568
SN - 1520-5134
ER -
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BibTex (up to 50 authors)
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@article{2024_Magsumov,
author = {Timur I Magsumov and Yaroslav E. Chumakov and Yurii Chumakov and Bulat R. Gainutdinov and R A Larionov and Askar K Gatiatulin and A K Gatiatulin and Ivan A Andreev and Nina K Ratmanova and Olga Ivanova and Igor V Trushkov and Igor A. Sedov},
title = {Solvation Properties of Triethylammonium-Based Protic Ionic Liquids},
journal = {Journal of Chemical & Engineering Data},
year = {2024},
volume = {70},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://pubs.acs.org/doi/10.1021/acs.jced.4c00442},
number = {1},
pages = {359--369},
doi = {10.1021/acs.jced.4c00442}
}
Cite this
MLA
Copy
Magsumov, Timur I., et al. “Solvation Properties of Triethylammonium-Based Protic Ionic Liquids.” Journal of Chemical & Engineering Data, vol. 70, no. 1, Nov. 2024, pp. 359-369. https://pubs.acs.org/doi/10.1021/acs.jced.4c00442.