Journal of Chemical Education, volume 99, issue 2, pages 1036-1043

Hands-on Electrochemical Reduction of CO2: Understanding Electrochemical Principles through Active Learning

Medvedev Jury J 1, 2
Tracey Chantal 2
Engelhardt Helen 1
Steksova Yulia 2
Krivoshapkin Pavel 2
1
 
Department of Chemistry, University of Waterloo, 200 University Avenue W, Waterloo, Ontario N2L 3G1, Canada
Publication typeJournal Article
Publication date2022-01-20
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor3
ISSN00219584, 19381328
General Chemistry
Education
Abstract
Electrochemistry represents a powerful sustainable method for chemical synthesis; however, its widespread application is limited due to the lack of exposure and appropriate basic training of synthetic chemists and engineers in electrochemistry and electrochemical engineering. The introduction of diverse laboratory practices to the current curricula will improve the understanding of electrochemistry and the theory behind its various applications. Here, we suggest an efficient laboratory experiment on the electrochemical reduction of CO2 to CO using inexpensive and readily available materials, such as metal wires, plastic vessels, batteries, and a hand-held CO detector. Students learn to assemble a divided electrochemical cell and perform important electrochemical reactions, such as electrochemical CO2 reduction and hydrogen evolution reaction. In this experiment, students analyze the rates of CO production under different electrolysis conditions and learn to understand the effects of operating parameters (applied potential, electrolyte concentration, and nature of the electrode) on the outcome of the reaction. This new comprehensive laboratory experiment is designed for students to better understand basic principles of electrochemistry and is suitable for undergraduate students.

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GOST Copy
Medvedev J. J. et al. Hands-on Electrochemical Reduction of CO2: Understanding Electrochemical Principles through Active Learning // Journal of Chemical Education. 2022. Vol. 99. No. 2. pp. 1036-1043.
GOST all authors (up to 50) Copy
Medvedev J. J., Tracey C., Engelhardt H., Steksova Y., Krivoshapkin P., Krivoshapkina E. F., Li F. Hands-on Electrochemical Reduction of CO2: Understanding Electrochemical Principles through Active Learning // Journal of Chemical Education. 2022. Vol. 99. No. 2. pp. 1036-1043.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.jchemed.1c01004
UR - https://doi.org/10.1021%2Facs.jchemed.1c01004
TI - Hands-on Electrochemical Reduction of CO2: Understanding Electrochemical Principles through Active Learning
T2 - Journal of Chemical Education
AU - Medvedev, Jury J
AU - Steksova, Yulia
AU - Krivoshapkin, Pavel
AU - Tracey, Chantal
AU - Engelhardt, Helen
AU - Krivoshapkina, Elena F.
AU - Li, Feng
PY - 2022
DA - 2022/01/20 00:00:00
PB - American Chemical Society (ACS)
SP - 1036-1043
IS - 2
VL - 99
SN - 0021-9584
SN - 1938-1328
ER -
BibTex |
Cite this
BibTex Copy
@article{2022_Medvedev,
author = {Jury J Medvedev and Yulia Steksova and Pavel Krivoshapkin and Chantal Tracey and Helen Engelhardt and Elena F. Krivoshapkina and Feng Li},
title = {Hands-on Electrochemical Reduction of CO2: Understanding Electrochemical Principles through Active Learning},
journal = {Journal of Chemical Education},
year = {2022},
volume = {99},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021%2Facs.jchemed.1c01004},
number = {2},
pages = {1036--1043},
doi = {10.1021/acs.jchemed.1c01004}
}
MLA
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MLA Copy
Medvedev, Jury J., et al. “Hands-on Electrochemical Reduction of CO2: Understanding Electrochemical Principles through Active Learning.” Journal of Chemical Education, vol. 99, no. 2, Jan. 2022, pp. 1036-1043. https://doi.org/10.1021%2Facs.jchemed.1c01004.
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