Copper-Catalyzed Preparation of Benzo[3,4]indolo[1,2-b]isoquinoline-8-ones and Photoluminescence Exploration
Тип публикации: Journal Article
Дата публикации: 2020-07-13
SCImago Q2
WOS Q1
БС1
SJR: 0.604
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
32657128
Organic Chemistry
Краткое описание
A facile synthesis of benzo[3,4]indolo[1,2-b]isoquinolin-8-ones is described. Under copper catalysis, the reaction proceeds with a high efficiency and a broad reaction scope. A deuteration experiment shows that the KIE value is 2.85. From the results on mechanism studies, copper-catalyzed C-H activation, intramolecular cis-addition of alkynes, and reductive elimination are involved. Moreover, this skeleton is indeed a new fluorophore, and its photophysical properties are also investigated.
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Hua Y. et al. Copper-Catalyzed Preparation of Benzo[3,4]indolo[1,2-b]isoquinoline-8-ones and Photoluminescence Exploration // Journal of Organic Chemistry. 2020. Vol. 85. No. 15. pp. 9614-9621.
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Hua Y., Chen Z., Diao H., Zhang L., Qiu G., Gao X., Zhou H. Copper-Catalyzed Preparation of Benzo[3,4]indolo[1,2-b]isoquinoline-8-ones and Photoluminescence Exploration // Journal of Organic Chemistry. 2020. Vol. 85. No. 15. pp. 9614-9621.
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TY - JOUR
DO - 10.1021/acs.joc.0c00936
UR - https://doi.org/10.1021/acs.joc.0c00936
TI - Copper-Catalyzed Preparation of Benzo[3,4]indolo[1,2-b]isoquinoline-8-ones and Photoluminescence Exploration
T2 - Journal of Organic Chemistry
AU - Hua, Yiwen
AU - Chen, Zi-Yan
AU - Diao, Hanying
AU - Zhang, Lianpeng
AU - Qiu, Guanyinsheng
AU - Gao, XiaoXing
AU - Zhou, Hongwei
PY - 2020
DA - 2020/07/13
PB - American Chemical Society (ACS)
SP - 9614-9621
IS - 15
VL - 85
PMID - 32657128
SN - 0022-3263
SN - 1520-6904
ER -
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@article{2020_Hua,
author = {Yiwen Hua and Zi-Yan Chen and Hanying Diao and Lianpeng Zhang and Guanyinsheng Qiu and XiaoXing Gao and Hongwei Zhou},
title = {Copper-Catalyzed Preparation of Benzo[3,4]indolo[1,2-b]isoquinoline-8-ones and Photoluminescence Exploration},
journal = {Journal of Organic Chemistry},
year = {2020},
volume = {85},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.joc.0c00936},
number = {15},
pages = {9614--9621},
doi = {10.1021/acs.joc.0c00936}
}
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MLA
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Hua, Yiwen, et al. “Copper-Catalyzed Preparation of Benzo[3,4]indolo[1,2-b]isoquinoline-8-ones and Photoluminescence Exploration.” Journal of Organic Chemistry, vol. 85, no. 15, Jul. 2020, pp. 9614-9621. https://doi.org/10.1021/acs.joc.0c00936.
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