1-(Phenylsulfonyl)-3-oxabicyclo[3.1.0]hexan-2-one as a Building Block in Organic Synthesis
1
Publication type: Journal Article
Publication date: 2018-09-06
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
30188126
Organic Chemistry
Abstract
The transformation of the readily available phenylsulfonyl lactone building block to structurally diverse molecular scaffolds is described. Depicted structures are accessed in one to three steps, and their overall yields are high. The rigidity of the starting building block greatly directs the stereoselectivity of the transformations, and newly generated stereogenic centers including the quaternary carbon centers are formed with high stereoselectivity generally superior to dr > 95:1.
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Konrádová D. et al. 1-(Phenylsulfonyl)-3-oxabicyclo[3.1.0]hexan-2-one as a Building Block in Organic Synthesis // Journal of Organic Chemistry. 2018. Vol. 83. No. 19. pp. 12229-12238.
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Konrádová D., Bon D. J. Y. D., Jicha M. 1-(Phenylsulfonyl)-3-oxabicyclo[3.1.0]hexan-2-one as a Building Block in Organic Synthesis // Journal of Organic Chemistry. 2018. Vol. 83. No. 19. pp. 12229-12238.
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TY - JOUR
DO - 10.1021/acs.joc.8b01625
UR - https://doi.org/10.1021/acs.joc.8b01625
TI - 1-(Phenylsulfonyl)-3-oxabicyclo[3.1.0]hexan-2-one as a Building Block in Organic Synthesis
T2 - Journal of Organic Chemistry
AU - Konrádová, Daniela
AU - Bon, David Jean Yves Denis
AU - Jicha, Miroslav
PY - 2018
DA - 2018/09/06
PB - American Chemical Society (ACS)
SP - 12229-12238
IS - 19
VL - 83
PMID - 30188126
SN - 0022-3263
SN - 1520-6904
ER -
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BibTex (up to 50 authors)
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@article{2018_Konrádová,
author = {Daniela Konrádová and David Jean Yves Denis Bon and Miroslav Jicha},
title = {1-(Phenylsulfonyl)-3-oxabicyclo[3.1.0]hexan-2-one as a Building Block in Organic Synthesis},
journal = {Journal of Organic Chemistry},
year = {2018},
volume = {83},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.joc.8b01625},
number = {19},
pages = {12229--12238},
doi = {10.1021/acs.joc.8b01625}
}
Cite this
MLA
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Konrádová, Daniela, et al. “1-(Phenylsulfonyl)-3-oxabicyclo[3.1.0]hexan-2-one as a Building Block in Organic Synthesis.” Journal of Organic Chemistry, vol. 83, no. 19, Sep. 2018, pp. 12229-12238. https://doi.org/10.1021/acs.joc.8b01625.