Revealing the Beneficial Effects of FeVO4 Nanoshell Layer on the BiVO4 Inverse Opal Core Layer for Photoelectrochemical Water Oxidation
Publication type: Journal Article
Publication date: 2017-03-30
scimago Q1
wos Q3
SJR: 0.914
CiteScore: 6.2
Impact factor: 3.2
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
In this paper we developed a template-assisted three-dimensionally ordered BiVO4 inverse opal (IO) film by sandwich-type infiltration through self-assembled colloidal polystyrene (PS) opal beads with a diameter of 410 nm (±20 nm) for photoelectrochemical hydrogen production. Herein, the ordered BiVO4 inverse opal structure possessed a pore diameter of ∼340 nm and wall thickness of ∼20 nm, providing a large surface area. Their photoelectrochemical behavior were assessed under 1 sun illumination (100 mW/cm2 with AM 1.5 filter) in 0.5 M Na2SO4 (pH 7) which displayed a photocurrent density (Jsc) of 0.8 mA/cm2 at 1.23 V vs a normal hydrogen electrode (NHE). Low photocurrents of BiVO4 IO photoelectrodes are due to their limited photoelectrochemical ability to split water under light irradiation and their intrinsically low electronic conductivities. To overcome these problems, BiVO4 IO film was modified to deposit a nanolayer of n-type FeVO4 having a narrow band gap (Eg = 2.06 eV). The bilayered BiVO4/FeVO4 core...
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56
Total citations:
56
Citations from 2024:
8
(14.29%)
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MLA
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GOST
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Balamurugan M. et al. Revealing the Beneficial Effects of FeVO4 Nanoshell Layer on the BiVO4 Inverse Opal Core Layer for Photoelectrochemical Water Oxidation // Journal of Physical Chemistry C. 2017. Vol. 121. No. 14. pp. 7625-7634.
GOST all authors (up to 50)
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Ahn K. Revealing the Beneficial Effects of FeVO4 Nanoshell Layer on the BiVO4 Inverse Opal Core Layer for Photoelectrochemical Water Oxidation // Journal of Physical Chemistry C. 2017. Vol. 121. No. 14. pp. 7625-7634.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.jpcc.6b12516
UR - https://doi.org/10.1021/acs.jpcc.6b12516
TI - Revealing the Beneficial Effects of FeVO4 Nanoshell Layer on the BiVO4 Inverse Opal Core Layer for Photoelectrochemical Water Oxidation
T2 - Journal of Physical Chemistry C
AU - Ahn, Kwang-Soon
PY - 2017
DA - 2017/03/30
PB - American Chemical Society (ACS)
SP - 7625-7634
IS - 14
VL - 121
SN - 1932-7447
SN - 1932-7455
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Balamurugan,
author = {Kwang-Soon Ahn},
title = {Revealing the Beneficial Effects of FeVO4 Nanoshell Layer on the BiVO4 Inverse Opal Core Layer for Photoelectrochemical Water Oxidation},
journal = {Journal of Physical Chemistry C},
year = {2017},
volume = {121},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.jpcc.6b12516},
number = {14},
pages = {7625--7634},
doi = {10.1021/acs.jpcc.6b12516}
}
Cite this
MLA
Copy
Balamurugan, Maheswari, et al. “Revealing the Beneficial Effects of FeVO4 Nanoshell Layer on the BiVO4 Inverse Opal Core Layer for Photoelectrochemical Water Oxidation.” Journal of Physical Chemistry C, vol. 121, no. 14, Mar. 2017, pp. 7625-7634. https://doi.org/10.1021/acs.jpcc.6b12516.