Journal of Physical Chemistry Letters, volume 11, issue 24, pages 10511-10518
Lithium Planar Deposition vs Whisker Growth: Crucial Role of Surface Diffusion
Publication type: Journal Article
Publication date: 2020-12-07
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.7
ISSN: 19487185
Physical and Theoretical Chemistry
General Materials Science
Abstract
Lithium plating-one of the critical processes in the desired high-energy lithium metal batteries-is accompanied by lithium whisker growth, which causes several problems that prevent the employment of metallic lithium anodes in rechargeable systems. They include low coulombic efficiency, electrolyte consumption, and the risk of short circuits, which can lead to thermal runaway of the battery. In recent years several strategies were suggested to mitigate whisker growth. The mechanism of this process, however, still lacks understanding. Here, we reveal the importance of surface diffusion along grain boundaries in solid lithium. We show that, at first, the plating of lithium onto a lithium substrate is possible as bulk crystal growth with a planar crystallization front for the Li grains with oblique (nonperpendicular to the surface) grain boundaries. Further, the developed compressive stress makes lithium diffusion to the grain base unfavorable, and new grains nucleate at the surface. The latter are the cause of the whisker growth from their roots. These findings indicate that the control of grain-boundary diffusion and grain size and structure paves the way to overcome the nonuniform morphology of plated lithium.
Citations by journals
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2
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Journal of the Electrochemical Society
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Journal of the Electrochemical Society
2 publications, 14.29%
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Acta Materialia
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Acta Materialia
1 publication, 7.14%
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Current Opinion in Solid State and Materials Science
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Current Opinion in Solid State and Materials Science
1 publication, 7.14%
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Materialia
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Materialia
1 publication, 7.14%
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Langmuir
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Langmuir
1 publication, 7.14%
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Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics
1 publication, 7.14%
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Energy and Environmental Science
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Energy and Environmental Science
1 publication, 7.14%
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Journal of Materials Chemistry A
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Journal of Materials Chemistry A
1 publication, 7.14%
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ACS Nano
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ACS Nano
1 publication, 7.14%
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European Physical Journal E
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European Physical Journal E
1 publication, 7.14%
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Small
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Small
1 publication, 7.14%
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Journal of Energy Storage
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Journal of Energy Storage
1 publication, 7.14%
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1
2
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Citations by publishers
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1
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4
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Elsevier
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Elsevier
4 publications, 28.57%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
3 publications, 21.43%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
2 publications, 14.29%
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The Electrochemical Society
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The Electrochemical Society
2 publications, 14.29%
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Springer Nature
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Springer Nature
1 publication, 7.14%
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Wiley
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Wiley
1 publication, 7.14%
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1
2
3
4
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Rulev A. A. et al. Lithium Planar Deposition vs Whisker Growth: Crucial Role of Surface Diffusion // Journal of Physical Chemistry Letters. 2020. Vol. 11. No. 24. pp. 10511-10518.
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Rulev A. A., Kondratyeva Y. O., Yashina L. V., Itkis D. Lithium Planar Deposition vs Whisker Growth: Crucial Role of Surface Diffusion // Journal of Physical Chemistry Letters. 2020. Vol. 11. No. 24. pp. 10511-10518.
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TY - JOUR
DO - 10.1021/acs.jpclett.0c02674
UR - https://doi.org/10.1021%2Facs.jpclett.0c02674
TI - Lithium Planar Deposition vs Whisker Growth: Crucial Role of Surface Diffusion
T2 - Journal of Physical Chemistry Letters
AU - Kondratyeva, Yevgeniya O
AU - Rulev, Alexey A
AU - Yashina, Lada V.
AU - Itkis, Daniil
PY - 2020
DA - 2020/12/07 00:00:00
PB - American Chemical Society (ACS)
SP - 10511-10518
IS - 24
VL - 11
SN - 1948-7185
ER -
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@article{2020_Rulev,
author = {Yevgeniya O Kondratyeva and Alexey A Rulev and Lada V. Yashina and Daniil Itkis},
title = {Lithium Planar Deposition vs Whisker Growth: Crucial Role of Surface Diffusion},
journal = {Journal of Physical Chemistry Letters},
year = {2020},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021%2Facs.jpclett.0c02674},
number = {24},
pages = {10511--10518},
doi = {10.1021/acs.jpclett.0c02674}
}
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Rulev, Alexey A., et al. “Lithium Planar Deposition vs Whisker Growth: Crucial Role of Surface Diffusion.” Journal of Physical Chemistry Letters, vol. 11, no. 24, Dec. 2020, pp. 10511-10518. https://doi.org/10.1021%2Facs.jpclett.0c02674.