Toward the Synthesis of Heteroleptic Zinc ROP Initiators Based on Pyridine-Containing Monoalcohols by Tuning Ligand Substituents
Badma N. Mankaev
1
,
B. N. Mankaev
1
,
K V Zaitsev
1
,
Maxim V Zabalov
2
,
EKATERINA A. ZAKHAROVA
1
,
Yuri F. Oprunenko
1
,
Galina S. Zaitseva
1
,
Sergey S. Karlov
1
Publication type: Journal Article
Publication date: 2023-03-20
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Synthesis of two types of complexes (heteroleptic vs homoleptic) is accomplished by an elegant variation of the ligand design. Heteroleptic ethyl zinc complexes 1a–3a were cleanly obtained via ethane elimination. Nevertheless, in the reaction of proligands 3 and 4 with Zn[N(SiMe3)2]2 performed at room temperature, only homoleptic complexes 3b and 4b can be isolated. Surprisingly, proligand 2 was found to cleanly produce amide heteroleptic zinc complex 2c in the reaction with Zn[N(SiMe3)2]2, and 2c seems to be the most promising in ring-opening polymerization (ROP) among tested initiators in terms of activity.
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Citations from 2024:
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Kuchuk E. A. et al. Toward the Synthesis of Heteroleptic Zinc ROP Initiators Based on Pyridine-Containing Monoalcohols by Tuning Ligand Substituents // Organometallics. 2023. Vol. 42. No. 18. pp. 2549-2557.
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Kuchuk E. A., Mankaev B. N., Mankaev B. N., Zaitsev K. V., Zaitsev K. V., Zabalov M. V., ZAKHAROVA E. A., Oprunenko Y. F., Churakov A. V., Lermontova E. K., Zaitseva G. S., Karlov S. S. Toward the Synthesis of Heteroleptic Zinc ROP Initiators Based on Pyridine-Containing Monoalcohols by Tuning Ligand Substituents // Organometallics. 2023. Vol. 42. No. 18. pp. 2549-2557.
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TY - JOUR
DO - 10.1021/acs.organomet.2c00611
UR - https://pubs.acs.org/doi/10.1021/acs.organomet.2c00611
TI - Toward the Synthesis of Heteroleptic Zinc ROP Initiators Based on Pyridine-Containing Monoalcohols by Tuning Ligand Substituents
T2 - Organometallics
AU - Kuchuk, Ekaterina A
AU - Mankaev, Badma N.
AU - Mankaev, B. N.
AU - Zaitsev, Kirill V.
AU - Zaitsev, K V
AU - Zabalov, Maxim V
AU - ZAKHAROVA, EKATERINA A.
AU - Oprunenko, Yuri F.
AU - Churakov, Andrei V.
AU - Lermontova, Elmira Kh.
AU - Zaitseva, Galina S.
AU - Karlov, Sergey S.
PY - 2023
DA - 2023/03/20
PB - American Chemical Society (ACS)
SP - 2549-2557
IS - 18
VL - 42
SN - 0276-7333
SN - 1520-6041
ER -
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BibTex (up to 50 authors)
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@article{2023_Kuchuk,
author = {Ekaterina A Kuchuk and Badma N. Mankaev and B. N. Mankaev and Kirill V. Zaitsev and K V Zaitsev and Maxim V Zabalov and EKATERINA A. ZAKHAROVA and Yuri F. Oprunenko and Andrei V. Churakov and Elmira Kh. Lermontova and Galina S. Zaitseva and Sergey S. Karlov},
title = {Toward the Synthesis of Heteroleptic Zinc ROP Initiators Based on Pyridine-Containing Monoalcohols by Tuning Ligand Substituents},
journal = {Organometallics},
year = {2023},
volume = {42},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://pubs.acs.org/doi/10.1021/acs.organomet.2c00611},
number = {18},
pages = {2549--2557},
doi = {10.1021/acs.organomet.2c00611}
}
Cite this
MLA
Copy
Kuchuk, Ekaterina A., et al. “Toward the Synthesis of Heteroleptic Zinc ROP Initiators Based on Pyridine-Containing Monoalcohols by Tuning Ligand Substituents.” Organometallics, vol. 42, no. 18, Mar. 2023, pp. 2549-2557. https://pubs.acs.org/doi/10.1021/acs.organomet.2c00611.