Reactions of Ruthenabenzene with Propynols Involving Hydrogen-Bonding-Induced [2 + 2] Cycloaddition
Publication type: Journal Article
Publication date: 2023-06-03
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Enyne metathesis reactions involving metallacyclobutene intermediates have been comprehensively studied and utilized in numerous synthetic processes and catalytic transformations. We describe here our initial results toward the utilization of metalla-aromatic in classical [2 + 2] cycloaddition that η3-allyl structures are formed stoichiometrically through hydrogen-bonding-induced [2 + 2] cycloaddition between several propynol and a ruthenabenzene complex. The effect of the intramolecular hydrogen bonding interaction was analyzed by experimental and computational studies.
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Lin Z. et al. Reactions of Ruthenabenzene with Propynols Involving Hydrogen-Bonding-Induced [2 + 2] Cycloaddition // Organometallics. 2023. Vol. 42. No. 13. pp. 1615-1620.
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Lin Z., Yan Z., Cai Y., Jian X., He N., Zhang H. Reactions of Ruthenabenzene with Propynols Involving Hydrogen-Bonding-Induced [2 + 2] Cycloaddition // Organometallics. 2023. Vol. 42. No. 13. pp. 1615-1620.
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TY - JOUR
DO - 10.1021/acs.organomet.3c00179
UR - https://pubs.acs.org/doi/10.1021/acs.organomet.3c00179
TI - Reactions of Ruthenabenzene with Propynols Involving Hydrogen-Bonding-Induced [2 + 2] Cycloaddition
T2 - Organometallics
AU - Lin, Zuzhang
AU - Yan, Zhewei
AU - Cai, Yapeng
AU - Jian, Xuan
AU - He, Nanxiang
AU - Zhang, Hong
PY - 2023
DA - 2023/06/03
PB - American Chemical Society (ACS)
SP - 1615-1620
IS - 13
VL - 42
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2023_Lin,
author = {Zuzhang Lin and Zhewei Yan and Yapeng Cai and Xuan Jian and Nanxiang He and Hong Zhang},
title = {Reactions of Ruthenabenzene with Propynols Involving Hydrogen-Bonding-Induced [2 + 2] Cycloaddition},
journal = {Organometallics},
year = {2023},
volume = {42},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://pubs.acs.org/doi/10.1021/acs.organomet.3c00179},
number = {13},
pages = {1615--1620},
doi = {10.1021/acs.organomet.3c00179}
}
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Lin, Zuzhang, et al. “Reactions of Ruthenabenzene with Propynols Involving Hydrogen-Bonding-Induced [2 + 2] Cycloaddition.” Organometallics, vol. 42, no. 13, Jun. 2023, pp. 1615-1620. https://pubs.acs.org/doi/10.1021/acs.organomet.3c00179.