Photoredox Metal-Free Allylic Defluorinative Silylation of α-Trifluoromethylstyrenes with Hydrosilanes
Publication type: Journal Article
Publication date: 2022-06-08
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
35674520
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
We report an efficient strategy that combines organic photoredox and hydrogen atom transfer to deliver gem-difluoroallylsilanes via defluorinative silylation of α-trifluoromethylstyrenes using hydrosilanes as silicon sources. This protocol provides an environmentally friendly approach for the preparation of structurally diverse gem-difluoroallylsilanes with excellent functional group compatibility and renders it suitable for late-stage modification of bioactive and complex molecules.
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52
Total citations:
52
Citations from 2025:
16
(30.77%)
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GOST
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Luo C. et al. Photoredox Metal-Free Allylic Defluorinative Silylation of α-Trifluoromethylstyrenes with Hydrosilanes // Organic Letters. 2022. Vol. 24. No. 23. pp. 4286-4291.
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Luo C., Zhou Y., Chen H., Wang T., Zhang Z. B., Han P., Jing L. H. Photoredox Metal-Free Allylic Defluorinative Silylation of α-Trifluoromethylstyrenes with Hydrosilanes // Organic Letters. 2022. Vol. 24. No. 23. pp. 4286-4291.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.2c01690
UR - https://doi.org/10.1021/acs.orglett.2c01690
TI - Photoredox Metal-Free Allylic Defluorinative Silylation of α-Trifluoromethylstyrenes with Hydrosilanes
T2 - Organic Letters
AU - Luo, Cong
AU - Zhou, Yang
AU - Chen, Hang
AU - Wang, Ting
AU - Zhang, Zheng Bing
AU - Han, Pan
AU - Jing, Lin Hai
PY - 2022
DA - 2022/06/08
PB - American Chemical Society (ACS)
SP - 4286-4291
IS - 23
VL - 24
PMID - 35674520
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Luo,
author = {Cong Luo and Yang Zhou and Hang Chen and Ting Wang and Zheng Bing Zhang and Pan Han and Lin Hai Jing},
title = {Photoredox Metal-Free Allylic Defluorinative Silylation of α-Trifluoromethylstyrenes with Hydrosilanes},
journal = {Organic Letters},
year = {2022},
volume = {24},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.orglett.2c01690},
number = {23},
pages = {4286--4291},
doi = {10.1021/acs.orglett.2c01690}
}
Cite this
MLA
Copy
Luo, Cong, et al. “Photoredox Metal-Free Allylic Defluorinative Silylation of α-Trifluoromethylstyrenes with Hydrosilanes.” Organic Letters, vol. 24, no. 23, Jun. 2022, pp. 4286-4291. https://doi.org/10.1021/acs.orglett.2c01690.