volume 25 issue 22 pages 4173-4176

Green Synthesis of α-Keton Thiol Ester via Photocatalytic Oxidative Radical Addition of Thioic Acid to Alkene

Publication typeJournal Article
Publication date2023-05-30
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
α-Keton sulfides are versatile building blocks in organic synthesis. From thioic acids and alkenes, we were able to develop the direct synthesis of α-keton thiol esters via photocatalytic oxidative radical additions. This reaction well matches the idea of green chemistry. It takes the advantage of thioxanthone as an inexpensive organic photocatalyst, O2 as a green oxidant, EtOAc as a green solvent, and visible light as a sustainable energy source, and the only byproduct is water.
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GOST Copy
Zhou X., Li R., Sun Z. Green Synthesis of α-Keton Thiol Ester via Photocatalytic Oxidative Radical Addition of Thioic Acid to Alkene // Organic Letters. 2023. Vol. 25. No. 22. pp. 4173-4176.
GOST all authors (up to 50) Copy
Zhou X., Li R., Sun Z. Green Synthesis of α-Keton Thiol Ester via Photocatalytic Oxidative Radical Addition of Thioic Acid to Alkene // Organic Letters. 2023. Vol. 25. No. 22. pp. 4173-4176.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.3c01481
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c01481
TI - Green Synthesis of α-Keton Thiol Ester via Photocatalytic Oxidative Radical Addition of Thioic Acid to Alkene
T2 - Organic Letters
AU - Zhou, Xiyan
AU - Li, Ruining
AU - Sun, Zhankui
PY - 2023
DA - 2023/05/30
PB - American Chemical Society (ACS)
SP - 4173-4176
IS - 22
VL - 25
PMID - 37249309
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Zhou,
author = {Xiyan Zhou and Ruining Li and Zhankui Sun},
title = {Green Synthesis of α-Keton Thiol Ester via Photocatalytic Oxidative Radical Addition of Thioic Acid to Alkene},
journal = {Organic Letters},
year = {2023},
volume = {25},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c01481},
number = {22},
pages = {4173--4176},
doi = {10.1021/acs.orglett.3c01481}
}
MLA
Cite this
MLA Copy
Zhou, Xiyan, et al. “Green Synthesis of α-Keton Thiol Ester via Photocatalytic Oxidative Radical Addition of Thioic Acid to Alkene.” Organic Letters, vol. 25, no. 22, May. 2023, pp. 4173-4176. https://pubs.acs.org/doi/10.1021/acs.orglett.3c01481.