Ni0-Catalyzed Regioselective [2 + 2 + 2] Cyclotrimerization of 1,3-Diynes: An Expeditious Synthesis of Hexasubstituted Alkynyl Benzenes
Publication type: Journal Article
Publication date: 2024-01-22
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
38252507
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
In the present work, we demonstrate a regioselective [2 + 2 + 2] cyclotrimerization of 1,3-diynes catalyzed by Ni0 to provide hexasubstituted benzenes (HSBs). HSBs have significant applications as functional materials and pharmaceuticals. The present protocol exhibited remarkable versatility, transforming 1,3-diynes with diverse alkyl, aryl, and heterocyclic groups to the corresponding HSBs. With the help of control experiments and density functional theory (DFT), the mechanism of the reaction and the origin of regioselectivity were elucidated.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
|
|
|
Organic Letters
3 publications, 30%
|
|
|
Chemical Communications
2 publications, 20%
|
|
|
Results in Chemistry
1 publication, 10%
|
|
|
ACS Applied Polymer Materials
1 publication, 10%
|
|
|
European Journal of Organic Chemistry
1 publication, 10%
|
|
|
Organic and Biomolecular Chemistry
1 publication, 10%
|
|
|
Advanced Synthesis and Catalysis
1 publication, 10%
|
|
|
1
2
3
|
Publishers
|
1
2
3
4
|
|
|
American Chemical Society (ACS)
4 publications, 40%
|
|
|
Royal Society of Chemistry (RSC)
3 publications, 30%
|
|
|
Wiley
2 publications, 20%
|
|
|
Elsevier
1 publication, 10%
|
|
|
1
2
3
4
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
10
Total citations:
10
Citations from 2024:
10
(100%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Chakrabortty R., Ghosh S., Venkata Prasanth B. Ni0-Catalyzed Regioselective [2 + 2 + 2] Cyclotrimerization of 1,3-Diynes: An Expeditious Synthesis of Hexasubstituted Alkynyl Benzenes // Organic Letters. 2024. Vol. 26. No. 4. pp. 792-797.
GOST all authors (up to 50)
Copy
Chakrabortty R., Ghosh S., Venkata Prasanth B. Ni0-Catalyzed Regioselective [2 + 2 + 2] Cyclotrimerization of 1,3-Diynes: An Expeditious Synthesis of Hexasubstituted Alkynyl Benzenes // Organic Letters. 2024. Vol. 26. No. 4. pp. 792-797.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.3c03863
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c03863
TI - Ni0-Catalyzed Regioselective [2 + 2 + 2] Cyclotrimerization of 1,3-Diynes: An Expeditious Synthesis of Hexasubstituted Alkynyl Benzenes
T2 - Organic Letters
AU - Chakrabortty, Rajesh
AU - Ghosh, Suman
AU - Venkata Prasanth, B.
PY - 2024
DA - 2024/01/22
PB - American Chemical Society (ACS)
SP - 792-797
IS - 4
VL - 26
PMID - 38252507
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2024_Chakrabortty,
author = {Rajesh Chakrabortty and Suman Ghosh and B. Venkata Prasanth},
title = {Ni0-Catalyzed Regioselective [2 + 2 + 2] Cyclotrimerization of 1,3-Diynes: An Expeditious Synthesis of Hexasubstituted Alkynyl Benzenes},
journal = {Organic Letters},
year = {2024},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c03863},
number = {4},
pages = {792--797},
doi = {10.1021/acs.orglett.3c03863}
}
Cite this
MLA
Copy
Chakrabortty, Rajesh, et al. “Ni0-Catalyzed Regioselective [2 + 2 + 2] Cyclotrimerization of 1,3-Diynes: An Expeditious Synthesis of Hexasubstituted Alkynyl Benzenes.” Organic Letters, vol. 26, no. 4, Jan. 2024, pp. 792-797. https://pubs.acs.org/doi/10.1021/acs.orglett.3c03863.