American Chemical Society (ACS)
Organic Letters
,  volume 26 ,  issue 5 ,  pages 1078-1082

Diazene-Catalyzed Oxidative Alkyl Halide–Olefin Metathesis

Publication type: Journal Article
Publication date: 2024-01-31
American Chemical Society (ACS)
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The first platform for oxidative alkyl halide–olefin metathesis is described. The procedure employs diazenes as catalysts, which effect the cyclization of alkenyl alkyl halides to generate cyclic olefins and carbonyl products. The synthesis of phenanthrene, coumarin, and quinolone derivatives is demonstrated as well as the potential to apply this strategy to other electrophiles.
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Kellner-Rogers J. S. et al. Diazene-Catalyzed Oxidative Alkyl Halide–Olefin Metathesis // Organic Letters. 2024. Vol. 26. No. 5. pp. 1078-1082.
GOST all authors (up to 50) Copy
Kellner-Rogers J. S., Kellner Rogers J. S., Wang R., Lambert T. H. Diazene-Catalyzed Oxidative Alkyl Halide–Olefin Metathesis // Organic Letters. 2024. Vol. 26. No. 5. pp. 1078-1082.
RIS |
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TY - JOUR
DO - 10.1021/acs.orglett.3c04309
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c04309
TI - Diazene-Catalyzed Oxidative Alkyl Halide–Olefin Metathesis
T2 - Organic Letters
AU - Kellner-Rogers, Julian S.
AU - Kellner Rogers, Julian S
AU - Wang, Rina
AU - Lambert, Tristan H
PY - 2024
DA - 2024/01/31
PB - American Chemical Society (ACS)
SP - 1078-1082
IS - 5
VL - 26
PMID - 38295157
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2024_Kellner-Rogers,
author = {Julian S. Kellner-Rogers and Julian S Kellner Rogers and Rina Wang and Tristan H Lambert},
title = {Diazene-Catalyzed Oxidative Alkyl Halide–Olefin Metathesis},
journal = {Organic Letters},
year = {2024},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c04309},
number = {5},
pages = {1078--1082},
doi = {10.1021/acs.orglett.3c04309}
}
MLA
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Kellner-Rogers, Julian S., et al. “Diazene-Catalyzed Oxidative Alkyl Halide–Olefin Metathesis.” Organic Letters, vol. 26, no. 5, Jan. 2024, pp. 1078-1082. https://pubs.acs.org/doi/10.1021/acs.orglett.3c04309.