Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes
Тип публикации: Journal Article
Дата публикации: 2024-07-29
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SJR: 1.007
CiteScore: 8.7
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ISSN: 15237060, 15237052
PubMed ID:
39069746
Краткое описание
A selective, metal-free synthesis of boron-functionalized indenes and benzofulvenes via BCl3-mediated cyclization of o-alkynylstyrenes is described. The method allows precise control over product formation by adjusting reaction conditions. These borylated products were utilized in diverse C–B bond derivatizations and in the total synthesis of Sulindac, a nonsteroidal anti-inflammatory drug, demonstrating the versatility and practicality of the developed methodology for synthetic applications.
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Humanes M. et al. Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes // Organic Letters. 2024. Vol. 26. No. 31. pp. 6568-6573.
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Humanes M., Sans-Panadés E., Virumbrales C., Milián A., Sanz R., García-García P., García García P., Fernández-Rodríguez M. A. Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes // Organic Letters. 2024. Vol. 26. No. 31. pp. 6568-6573.
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TY - JOUR
DO - 10.1021/acs.orglett.4c02092
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.4c02092
TI - Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes
T2 - Organic Letters
AU - Humanes, Marcos
AU - Sans-Panadés, Ester
AU - Virumbrales, Cintia
AU - Milián, Ana
AU - Sanz, Roberto
AU - García-García, Patricia
AU - García García, Patricia
AU - Fernández-Rodríguez, Manuel A.
PY - 2024
DA - 2024/07/29
PB - American Chemical Society (ACS)
SP - 6568-6573
IS - 31
VL - 26
PMID - 39069746
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2024_Humanes,
author = {Marcos Humanes and Ester Sans-Panadés and Cintia Virumbrales and Ana Milián and Roberto Sanz and Patricia García-García and Patricia García García and Manuel A. Fernández-Rodríguez},
title = {Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes},
journal = {Organic Letters},
year = {2024},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.4c02092},
number = {31},
pages = {6568--6573},
doi = {10.1021/acs.orglett.4c02092}
}
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Humanes, Marcos, et al. “Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes.” Organic Letters, vol. 26, no. 31, Jul. 2024, pp. 6568-6573. https://pubs.acs.org/doi/10.1021/acs.orglett.4c02092.
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