Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes
Marcos Humanes
1
,
Ester Sans-Panadés
1
,
Cintia Virumbrales
2
,
Ana Milián
1
,
Roberto Sanz
2
,
Patricia García-García
1
,
Patricia García García
1
,
Manuel A. Fernández-Rodríguez
1
1
Publication type: Journal Article
Publication date: 2024-07-29
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
39069746
Abstract
A selective, metal-free synthesis of boron-functionalized indenes and benzofulvenes via BCl3-mediated cyclization of o-alkynylstyrenes is described. The method allows precise control over product formation by adjusting reaction conditions. These borylated products were utilized in diverse C–B bond derivatizations and in the total synthesis of Sulindac, a nonsteroidal anti-inflammatory drug, demonstrating the versatility and practicality of the developed methodology for synthetic applications.
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7
Total citations:
7
Citations from 2025:
6
(85.72%)
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GOST
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Humanes M. et al. Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes // Organic Letters. 2024. Vol. 26. No. 31. pp. 6568-6573.
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Humanes M., Sans-Panadés E., Virumbrales C., Milián A., Sanz R., García-García P., García García P., Fernández-Rodríguez M. A. Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes // Organic Letters. 2024. Vol. 26. No. 31. pp. 6568-6573.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.4c02092
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.4c02092
TI - Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes
T2 - Organic Letters
AU - Humanes, Marcos
AU - Sans-Panadés, Ester
AU - Virumbrales, Cintia
AU - Milián, Ana
AU - Sanz, Roberto
AU - García-García, Patricia
AU - García García, Patricia
AU - Fernández-Rodríguez, Manuel A.
PY - 2024
DA - 2024/07/29
PB - American Chemical Society (ACS)
SP - 6568-6573
IS - 31
VL - 26
PMID - 39069746
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2024_Humanes,
author = {Marcos Humanes and Ester Sans-Panadés and Cintia Virumbrales and Ana Milián and Roberto Sanz and Patricia García-García and Patricia García García and Manuel A. Fernández-Rodríguez},
title = {Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes},
journal = {Organic Letters},
year = {2024},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.4c02092},
number = {31},
pages = {6568--6573},
doi = {10.1021/acs.orglett.4c02092}
}
Cite this
MLA
Copy
Humanes, Marcos, et al. “Selective Synthesis of Boron-Functionalized Indenes and Benzofulvenes by BCl3-Promoted Cyclizations of ortho-Alkynylstyrenes.” Organic Letters, vol. 26, no. 31, Jul. 2024, pp. 6568-6573. https://pubs.acs.org/doi/10.1021/acs.orglett.4c02092.
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