Five-Component [2 + 2 + 1 + 1] Tandem Benzannulation Leading to Multifunctionalized Aromatic Amines
Publication type: Journal Article
Publication date: 2024-11-01
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
39485862
Abstract
An unprecedented five-component [2 + 2 + 1 + 1] benzannulation strategy for regioselective assembly of densely functionalized aromatic amines from two ynals, two malononitriles, and sodium sulfinates is established. The benzannulation protocol enables the efficient installation of five substituents on a benzene ring via the formation of multiple chemical bonds in a single operation, providing various multifunctionalized aromatic primary amines in moderate to good yields. Additionally, three-component [3 + 2 + 1] cycloaddition of malononitriles, ynals, and NH4SCN was also achieved to produce 2-amnopyridine derivatives with NH4SCN serving as an ammonia surrogate.
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7
Total citations:
7
Citations from 2024:
7
(100%)
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Wang H. et al. Five-Component [2 + 2 + 1 + 1] Tandem Benzannulation Leading to Multifunctionalized Aromatic Amines // Organic Letters. 2024. Vol. 26. No. 45. pp. 9648-9653.
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Wang H., Li S., Wu X., Chen T., Liu W., Liu X., Cao H. Five-Component [2 + 2 + 1 + 1] Tandem Benzannulation Leading to Multifunctionalized Aromatic Amines // Organic Letters. 2024. Vol. 26. No. 45. pp. 9648-9653.
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TY - JOUR
DO - 10.1021/acs.orglett.4c03299
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.4c03299
TI - Five-Component [2 + 2 + 1 + 1] Tandem Benzannulation Leading to Multifunctionalized Aromatic Amines
T2 - Organic Letters
AU - Wang, Hexiang
AU - Li, Shuting
AU - Wu, Xiaoying
AU - Chen, Tiantian
AU - Liu, Wenjie
AU - Liu, Xiang
AU - Cao, Hua
PY - 2024
DA - 2024/11/01
PB - American Chemical Society (ACS)
SP - 9648-9653
IS - 45
VL - 26
PMID - 39485862
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2024_Wang,
author = {Hexiang Wang and Shuting Li and Xiaoying Wu and Tiantian Chen and Wenjie Liu and Xiang Liu and Hua Cao},
title = {Five-Component [2 + 2 + 1 + 1] Tandem Benzannulation Leading to Multifunctionalized Aromatic Amines},
journal = {Organic Letters},
year = {2024},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.4c03299},
number = {45},
pages = {9648--9653},
doi = {10.1021/acs.orglett.4c03299}
}
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MLA
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Wang, Hexiang, et al. “Five-Component [2 + 2 + 1 + 1] Tandem Benzannulation Leading to Multifunctionalized Aromatic Amines.” Organic Letters, vol. 26, no. 45, Nov. 2024, pp. 9648-9653. https://pubs.acs.org/doi/10.1021/acs.orglett.4c03299.