Biocatalyzed and Photochemical Formal [2+2] Cycloaddition of Euphoboetirane A: A Route to a Fused Pentacyclic Diterpene Skeleton
Fátima Vela Benavides
1
,
Marija Kirić
1
,
Felipe Escobar-Montaño
1
,
Antonio J. Macı́as-Sánchez
1, 2
,
Hernando Bolivar-Anillo
3, 4, 5, 6
,
Hernando José Bolívar Anillo
5, 6
,
José Manuel Botubol Ares
1, 7
,
Rosa Durán-Patrón
1, 2
,
R. H. Galan
1, 2
3
Laboratorio de Investigación en Microbiología, Facultad de Ciencias Básicas y Biomédicas
4
Universidad Simón Bolivar
|
5
Laboratorio de Investigación en Microbiología, Facultad de Ciencias Básicas y Biomédicas, Barranquilla, Colombia
|
6
Universidad Simón Bolivar, Barranquilla, Colombia
|
Publication type: Journal Article
Publication date: 2025-02-02
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
Abstract
Cycloeuphoboetirane A (2), a new diterpene with an unprecedented pentacyclic skeleton, has been obtained from lathyrane euphoboetirane A (1). A formal intramolecular [2+2] cycloaddition reaction catalyzed by Sordaria tomento-alba ST1-UCA is involved, providing new evidence for the existence of enzymes capable of catalyzing this reaction. A biomimetic photochemical conversion was also achieved by benzophenone with light-emitting diode irradiation.
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Vela Benavides F. et al. Biocatalyzed and Photochemical Formal [2+2] Cycloaddition of Euphoboetirane A: A Route to a Fused Pentacyclic Diterpene Skeleton // Organic Letters. 2025. Vol. 27. No. 6. pp. 1407-1411.
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Vela Benavides F., Kirić M., Escobar-Montaño F., Macı́as-Sánchez A. J., Bolivar-Anillo H., Bolívar Anillo H. J., Botubol Ares J. M., Durán-Patrón R., Galan R. H. Biocatalyzed and Photochemical Formal [2+2] Cycloaddition of Euphoboetirane A: A Route to a Fused Pentacyclic Diterpene Skeleton // Organic Letters. 2025. Vol. 27. No. 6. pp. 1407-1411.
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TY - JOUR
DO - 10.1021/acs.orglett.4c04724
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.4c04724
TI - Biocatalyzed and Photochemical Formal [2+2] Cycloaddition of Euphoboetirane A: A Route to a Fused Pentacyclic Diterpene Skeleton
T2 - Organic Letters
AU - Vela Benavides, Fátima
AU - Kirić, Marija
AU - Escobar-Montaño, Felipe
AU - Macı́as-Sánchez, Antonio J.
AU - Bolivar-Anillo, Hernando
AU - Bolívar Anillo, Hernando José
AU - Botubol Ares, José Manuel
AU - Durán-Patrón, Rosa
AU - Galan, R. H.
PY - 2025
DA - 2025/02/02
PB - American Chemical Society (ACS)
SP - 1407-1411
IS - 6
VL - 27
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2025_Vela Benavides,
author = {Fátima Vela Benavides and Marija Kirić and Felipe Escobar-Montaño and Antonio J. Macı́as-Sánchez and Hernando Bolivar-Anillo and Hernando José Bolívar Anillo and José Manuel Botubol Ares and Rosa Durán-Patrón and R. H. Galan},
title = {Biocatalyzed and Photochemical Formal [2+2] Cycloaddition of Euphoboetirane A: A Route to a Fused Pentacyclic Diterpene Skeleton},
journal = {Organic Letters},
year = {2025},
volume = {27},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.4c04724},
number = {6},
pages = {1407--1411},
doi = {10.1021/acs.orglett.4c04724}
}
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MLA
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Vela Benavides, Fátima, et al. “Biocatalyzed and Photochemical Formal [2+2] Cycloaddition of Euphoboetirane A: A Route to a Fused Pentacyclic Diterpene Skeleton.” Organic Letters, vol. 27, no. 6, Feb. 2025, pp. 1407-1411. https://pubs.acs.org/doi/10.1021/acs.orglett.4c04724.