A Highly Active PN3 Manganese Pincer Complex Performing N-Alkylation of Amines under Mild Conditions
Publication type: Journal Article
Publication date: 2019-04-15
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
30986073
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A highly active Mn(I) catalyst based on a nonsymmetric PN3-ligand scaffold for the N-alkylation of amines with alcohols utilizing the borrowing hydrogen methodology is reported. A broad range of anilines and the more challenging aliphatic amines were alkylated with primary and secondary alcohols. Moreover, the combination of low catalyst loadings and mild reaction conditions provides high efficiency for this atom-economic transformation.
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82
Total citations:
82
Citations from 2024:
30
(36%)
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GOST
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Homberg L., Roller A., Hultzsch K. C. A Highly Active PN3 Manganese Pincer Complex Performing N-Alkylation of Amines under Mild Conditions // Organic Letters. 2019. Vol. 21. No. 9. pp. 3142-3147.
GOST all authors (up to 50)
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Homberg L., Roller A., Hultzsch K. C. A Highly Active PN3 Manganese Pincer Complex Performing N-Alkylation of Amines under Mild Conditions // Organic Letters. 2019. Vol. 21. No. 9. pp. 3142-3147.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.9b00832
UR - https://doi.org/10.1021/acs.orglett.9b00832
TI - A Highly Active PN3 Manganese Pincer Complex Performing N-Alkylation of Amines under Mild Conditions
T2 - Organic Letters
AU - Homberg, Leonard
AU - Roller, Alexander
AU - Hultzsch, Kai C.
PY - 2019
DA - 2019/04/15
PB - American Chemical Society (ACS)
SP - 3142-3147
IS - 9
VL - 21
PMID - 30986073
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Homberg,
author = {Leonard Homberg and Alexander Roller and Kai C. Hultzsch},
title = {A Highly Active PN3 Manganese Pincer Complex Performing N-Alkylation of Amines under Mild Conditions},
journal = {Organic Letters},
year = {2019},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.orglett.9b00832},
number = {9},
pages = {3142--3147},
doi = {10.1021/acs.orglett.9b00832}
}
Cite this
MLA
Copy
Homberg, Leonard, et al. “A Highly Active PN3 Manganese Pincer Complex Performing N-Alkylation of Amines under Mild Conditions.” Organic Letters, vol. 21, no. 9, Apr. 2019, pp. 3142-3147. https://doi.org/10.1021/acs.orglett.9b00832.