ACS Applied Energy Materials, volume 3, issue 9, pages 9401-9407

4H-[1,2,3]Triazolo[4,5-c][1,2,5]oxadiazole 5-oxide and Its Salts: Promising Multipurpose Energetic Materials

Pivkina Alla 3
Strelenko Yuri A. 1
Lempert David 4
Tartakovsky Vladimir A 1
Publication typeJournal Article
Publication date2020-09-03
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor6.4
ISSN25740962
Materials Chemistry
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Chemical Engineering (miscellaneous)
Abstract
A smooth synthesis of 4H-[1,2,3]triazolo[4,5-c][1,2,5]oxadiazole 5-oxide 1 and its energetic salts (ammonium, hydroxylammonium, guanidinium, triaminoguanidinium) is reported. The compounds synthesized were characterized by multinuclear nuclear magnetic resonance (NMR) and infrared (IR) spectroscopy, mass spectrometry, elemental analysis, differential scanning calorimetry, single-crystal, and powder X-ray diffraction. All the compounds possess a beneficially high enthalpy of formation (88.9–168.0 kcal·mol–1). These data, in combination with the experimentally determined densities (1.702–1.934 g·cm–1), were used to calculate the detonation pressures (33.9–43.1 GPa) and velocities (8.86–9.31 km·s–1). The majority of the synthesized energetic salts had moderate impact and friction sensitivity, which made them promising candidates for various energy applications, including their use as components of solid composite propellants. It was shown that compounds 1 and 2c–f had higher energetic characteristics as components of solid composite propellants (the specific impulse was higher by 5–10 s) than HMX or CL-20 in propellant formulations.

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Voronin A. A. et al. 4H-[1,2,3]Triazolo[4,5-c][1,2,5]oxadiazole 5-oxide and Its Salts: Promising Multipurpose Energetic Materials // ACS Applied Energy Materials. 2020. Vol. 3. No. 9. pp. 9401-9407.
GOST all authors (up to 50) Copy
Voronin A. A., Fedyanin I. V., Churakov A. M., Pivkina A., Muravyev N., Strelenko Y. A., Klenov M. S., Lempert D., Tartakovsky V. A. 4H-[1,2,3]Triazolo[4,5-c][1,2,5]oxadiazole 5-oxide and Its Salts: Promising Multipurpose Energetic Materials // ACS Applied Energy Materials. 2020. Vol. 3. No. 9. pp. 9401-9407.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acsaem.0c01769
UR - https://doi.org/10.1021%2Facsaem.0c01769
TI - 4H-[1,2,3]Triazolo[4,5-c][1,2,5]oxadiazole 5-oxide and Its Salts: Promising Multipurpose Energetic Materials
T2 - ACS Applied Energy Materials
AU - Tartakovsky, Vladimir A
AU - Voronin, Alexey A
AU - Strelenko, Yuri A.
AU - Klenov, Michael S
AU - Fedyanin, Ivan V.
AU - Churakov, Aleksandr M
AU - Pivkina, Alla
AU - Muravyev, Nikita
AU - Lempert, David
PY - 2020
DA - 2020/09/03 00:00:00
PB - American Chemical Society (ACS)
SP - 9401-9407
IS - 9
VL - 3
SN - 2574-0962
ER -
BibTex |
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BibTex Copy
@article{2020_Voronin,
author = {Vladimir A Tartakovsky and Alexey A Voronin and Yuri A. Strelenko and Michael S Klenov and Ivan V. Fedyanin and Aleksandr M Churakov and Alla Pivkina and Nikita Muravyev and David Lempert},
title = {4H-[1,2,3]Triazolo[4,5-c][1,2,5]oxadiazole 5-oxide and Its Salts: Promising Multipurpose Energetic Materials},
journal = {ACS Applied Energy Materials},
year = {2020},
volume = {3},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021%2Facsaem.0c01769},
number = {9},
pages = {9401--9407},
doi = {10.1021/acsaem.0c01769}
}
MLA
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MLA Copy
Voronin, Alexey A., et al. “4H-[1,2,3]Triazolo[4,5-c][1,2,5]oxadiazole 5-oxide and Its Salts: Promising Multipurpose Energetic Materials.” ACS Applied Energy Materials, vol. 3, no. 9, Sep. 2020, pp. 9401-9407. https://doi.org/10.1021%2Facsaem.0c01769.
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