4-Benzoylamino-3-hydroxybutyric Acid, Historically First “Anomalous Racemate”: Reinvestigation
Publication type: Journal Article
Publication date: 2015-02-20
scimago Q2
wos Q1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Chiral 4-benzoylamino-3-hydroxybutyric acid (1) was recognized in 1930 as the first example of “anomalous racemates” (correct to say, anomalous conglomerates), that is, specific addition compounds formed by different enantiomers in unequal ratio. Through the comparative (racemic against homochiral samples) inspection of the IR spectra, single crystal X-ray diffraction, PXRD analysis, and solubility data we have found that this substance forms normal racemic compound in the solid state, and must be excluded from the very short list of anomalous conglomerates. At the same time homo-1 is dissolved in 25 times better than rac-1, and this feature belongs to another interesting and rare type, namely, “anticonglomerates”. Some of the reasons for this behavior are discussed.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
CrystEngComm
2 publications, 40%
|
|
|
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
1 publication, 20%
|
|
|
Chemical Engineering and Technology
1 publication, 20%
|
|
|
Lecture Notes in Earth System Sciences
1 publication, 20%
|
|
|
1
2
|
Publishers
|
1
2
|
|
|
Royal Society of Chemistry (RSC)
2 publications, 40%
|
|
|
International Union of Crystallography (IUCr)
1 publication, 20%
|
|
|
Wiley
1 publication, 20%
|
|
|
Springer Nature
1 publication, 20%
|
|
|
1
2
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
5
Total citations:
5
Citations from 2024:
0
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Bredikhin A. A. et al. 4-Benzoylamino-3-hydroxybutyric Acid, Historically First “Anomalous Racemate”: Reinvestigation // Crystal Growth and Design. 2015. Vol. 15. No. 3. pp. 1362-1373.
GOST all authors (up to 50)
Copy
Bredikhin A. A., Bredikhina Z. A., Zakharychev D. V., Samigullina A. I., Gubaidullin A. T. 4-Benzoylamino-3-hydroxybutyric Acid, Historically First “Anomalous Racemate”: Reinvestigation // Crystal Growth and Design. 2015. Vol. 15. No. 3. pp. 1362-1373.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/cg5017615
UR - https://doi.org/10.1021/cg5017615
TI - 4-Benzoylamino-3-hydroxybutyric Acid, Historically First “Anomalous Racemate”: Reinvestigation
T2 - Crystal Growth and Design
AU - Bredikhin, Alexander A.
AU - Bredikhina, Zemfira A.
AU - Zakharychev, Dmitry V.
AU - Samigullina, Aida I.
AU - Gubaidullin, Aidar T.
PY - 2015
DA - 2015/02/20
PB - American Chemical Society (ACS)
SP - 1362-1373
IS - 3
VL - 15
SN - 1528-7483
SN - 1528-7505
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Bredikhin,
author = {Alexander A. Bredikhin and Zemfira A. Bredikhina and Dmitry V. Zakharychev and Aida I. Samigullina and Aidar T. Gubaidullin},
title = {4-Benzoylamino-3-hydroxybutyric Acid, Historically First “Anomalous Racemate”: Reinvestigation},
journal = {Crystal Growth and Design},
year = {2015},
volume = {15},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/cg5017615},
number = {3},
pages = {1362--1373},
doi = {10.1021/cg5017615}
}
Cite this
MLA
Copy
Bredikhin, Alexander A., et al. “4-Benzoylamino-3-hydroxybutyric Acid, Historically First “Anomalous Racemate”: Reinvestigation.” Crystal Growth and Design, vol. 15, no. 3, Feb. 2015, pp. 1362-1373. https://doi.org/10.1021/cg5017615.