том 34 издание 3 страницы 730-740

Integral Analysis of Methyl tert-Butyl Ether Synthesis Kinetics

Tiejun Zhang
Ravindra Datta
Тип публикацииJournal Article
Дата публикации1995-03-01
scimago Q1
wos Q2
БС1
SJR0.828
CiteScore6.7
Impact factor3.9
ISSN08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Краткое описание
Kinetics of the liquid phase synthesis of methyl tert-butyl ether (MTBE) from methanol and isobutylene were studied experimentally in an isothermal integral packed-bed reactor over a commercial ion exchange resin catalyst, Amberlyst 15, under conditions corresponding to those encountered in industrial practice. The reaction equilibrium was also studied experimentally and an expression for the equilibrium constant is proposed. The intrinsic kinetics were determined under conditions free of diffusional influence. The resulting effective activation energy, 85.4 kJ/mol, is about the average of those reported in the literature. Next, intraparticle diffusional limitations were investigated for compositions close to the stoichiometric feed and the results indicate that, with Amberlyst 15 catalyst of average diameter 0.74 mm, the reaction is substantially limited by intraparticle diffusion resistance at temperatures above 333 K and at isobutylene conversions closer to the equilibrium.
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ГОСТ |
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Zhang T., Datta R. Integral Analysis of Methyl tert-Butyl Ether Synthesis Kinetics // Industrial & Engineering Chemistry Research. 1995. Vol. 34. No. 3. pp. 730-740.
ГОСТ со всеми авторами (до 50) Скопировать
Zhang T., Datta R. Integral Analysis of Methyl tert-Butyl Ether Synthesis Kinetics // Industrial & Engineering Chemistry Research. 1995. Vol. 34. No. 3. pp. 730-740.
RIS |
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TY - JOUR
DO - 10.1021/ie00042a004
UR - https://doi.org/10.1021/ie00042a004
TI - Integral Analysis of Methyl tert-Butyl Ether Synthesis Kinetics
T2 - Industrial & Engineering Chemistry Research
AU - Zhang, Tiejun
AU - Datta, Ravindra
PY - 1995
DA - 1995/03/01
PB - American Chemical Society (ACS)
SP - 730-740
IS - 3
VL - 34
SN - 0888-5885
SN - 1520-5045
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{1995_Zhang,
author = {Tiejun Zhang and Ravindra Datta},
title = {Integral Analysis of Methyl tert-Butyl Ether Synthesis Kinetics},
journal = {Industrial & Engineering Chemistry Research},
year = {1995},
volume = {34},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ie00042a004},
number = {3},
pages = {730--740},
doi = {10.1021/ie00042a004}
}
MLA
Цитировать
Zhang, Tiejun, and Ravindra Datta. “Integral Analysis of Methyl tert-Butyl Ether Synthesis Kinetics.” Industrial & Engineering Chemistry Research, vol. 34, no. 3, Mar. 1995, pp. 730-740. https://doi.org/10.1021/ie00042a004.