Mechanistic Analysis of Intramolecular Free Radical Reactions toward Synthesis of 7-Azabicyclo[2.2.1]heptane Derivatives
Тип публикации: Journal Article
Дата публикации: 2009-04-29
SCImago Q2
WOS Q1
БС1
SJR: 0.604
CiteScore: 5.8
Impact factor: 3.3
ISSN: 00223263, 15206904
PubMed ID:
19402620
Organic Chemistry
Краткое описание
The mechanisms for the formation of conformationally constrained epibatidine analogues by intramolecular free radical processes have been computationally addressed by means of DFT methods. The mechanism and the critical effect of the 7-nitrogen protecting group on the outcome of these radical-mediated cyclizations are discussed. Theoretical findings account for unexpected experimental results and can assist in the selection of proper precursors for a successful cyclization.
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Soriano E., Marco-Contelles J. Mechanistic Analysis of Intramolecular Free Radical Reactions toward Synthesis of 7-Azabicyclo[2.2.1]heptane Derivatives // Journal of Organic Chemistry. 2009. Vol. 74. No. 11. pp. 4061-4067.
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Soriano E., Marco-Contelles J. Mechanistic Analysis of Intramolecular Free Radical Reactions toward Synthesis of 7-Azabicyclo[2.2.1]heptane Derivatives // Journal of Organic Chemistry. 2009. Vol. 74. No. 11. pp. 4061-4067.
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TY - JOUR
DO - 10.1021/jo900225f
UR - https://doi.org/10.1021/jo900225f
TI - Mechanistic Analysis of Intramolecular Free Radical Reactions toward Synthesis of 7-Azabicyclo[2.2.1]heptane Derivatives
T2 - Journal of Organic Chemistry
AU - Soriano, Elena
AU - Marco-Contelles, Jose
PY - 2009
DA - 2009/04/29
PB - American Chemical Society (ACS)
SP - 4061-4067
IS - 11
VL - 74
PMID - 19402620
SN - 0022-3263
SN - 1520-6904
ER -
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@article{2009_Soriano,
author = {Elena Soriano and Jose Marco-Contelles},
title = {Mechanistic Analysis of Intramolecular Free Radical Reactions toward Synthesis of 7-Azabicyclo[2.2.1]heptane Derivatives},
journal = {Journal of Organic Chemistry},
year = {2009},
volume = {74},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/jo900225f},
number = {11},
pages = {4061--4067},
doi = {10.1021/jo900225f}
}
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Soriano, Elena, and Jose Marco-Contelles. “Mechanistic Analysis of Intramolecular Free Radical Reactions toward Synthesis of 7-Azabicyclo[2.2.1]heptane Derivatives.” Journal of Organic Chemistry, vol. 74, no. 11, Apr. 2009, pp. 4061-4067. https://doi.org/10.1021/jo900225f.
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