Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides
O M Mulina
1
,
Nataliya V Zhironkina
1, 2
,
Publication type: Journal Article
Publication date: 2020-02-20
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
32077294
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Sulfonylated N-unsubstituted enamines were synthesized through a chain of chemical and electrochemical transformations via sulfonylation of vinyl azides. The disclosing of the N-unsubstituted enamines synthesis was based on a unique property of the azido group, which is its ability to eliminate the N2 molecule. Furthermore, a formal paradox is observed: a double bond reacts and a double bond is retained. Electrosynthesis proceeded in an undivided cell equipped with a graphite anode and a stainless steel cathode; NH4I was used as a supporting electrolyte.
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63
Total citations:
63
Citations from 2024:
11
(17%)
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GOST
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Mulina O. M. et al. Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides // Organic Letters. 2020. Vol. 22. No. 5. pp. 1818-1824.
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Mulina O. M., Zhironkina N. V., Paveliev S. A., Demchuk D. V., Terent'ev A. O. Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides // Organic Letters. 2020. Vol. 22. No. 5. pp. 1818-1824.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ACS.ORGLETT.0C00139
UR - https://doi.org/10.1021/ACS.ORGLETT.0C00139
TI - Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides
T2 - Organic Letters
AU - Mulina, O M
AU - Zhironkina, Nataliya V
AU - Paveliev, Stanislav A
AU - Demchuk, Dmitry V.
AU - Terent'ev, Alexander O.
PY - 2020
DA - 2020/02/20
PB - American Chemical Society (ACS)
SP - 1818-1824
IS - 5
VL - 22
PMID - 32077294
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Mulina,
author = {O M Mulina and Nataliya V Zhironkina and Stanislav A Paveliev and Dmitry V. Demchuk and Alexander O. Terent'ev},
title = {Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides},
journal = {Organic Letters},
year = {2020},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ACS.ORGLETT.0C00139},
number = {5},
pages = {1818--1824},
doi = {10.1021/ACS.ORGLETT.0C00139}
}
Cite this
MLA
Copy
Mulina, O. M., et al. “Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides.” Organic Letters, vol. 22, no. 5, Feb. 2020, pp. 1818-1824. https://doi.org/10.1021/ACS.ORGLETT.0C00139.