volume 22 issue 23 pages 9376-9380

Site-Selective Functionalization of 7-Azaindoles via Carbene Transfer and Isolation of N-Aromatic Zwitterions

Publication typeJournal Article
Publication date2020-11-24
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The first systematic study on metal-carbene transfer reaction of 7-azaindoles has been conducted, and the unprecedented dearomative N7-alkylation reaction has been accomplished via ruthenium catalysis. Importantly, through a sequential dearomatization-aromatization process, an isolable, and new class of azaindole-based N-aromatic zwitterions has been discovered from the reaction of 7-azaindoles and diazoesters.
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GOST Copy
Liu J. et al. Site-Selective Functionalization of 7-Azaindoles via Carbene Transfer and Isolation of N-Aromatic Zwitterions // Organic Letters. 2020. Vol. 22. No. 23. pp. 9376-9380.
GOST all authors (up to 50) Copy
Liu J., Xu G., Tang S., Chen Q., Sun J. Site-Selective Functionalization of 7-Azaindoles via Carbene Transfer and Isolation of N-Aromatic Zwitterions // Organic Letters. 2020. Vol. 22. No. 23. pp. 9376-9380.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.0c03653
UR - https://doi.org/10.1021/acs.orglett.0c03653
TI - Site-Selective Functionalization of 7-Azaindoles via Carbene Transfer and Isolation of N-Aromatic Zwitterions
T2 - Organic Letters
AU - Liu, Junheng
AU - Xu, Guangyang
AU - Tang, Shengbiao
AU - Chen, Qun
AU - Sun, Jiangtao
PY - 2020
DA - 2020/11/24
PB - American Chemical Society (ACS)
SP - 9376-9380
IS - 23
VL - 22
PMID - 33231470
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Liu,
author = {Junheng Liu and Guangyang Xu and Shengbiao Tang and Qun Chen and Jiangtao Sun},
title = {Site-Selective Functionalization of 7-Azaindoles via Carbene Transfer and Isolation of N-Aromatic Zwitterions},
journal = {Organic Letters},
year = {2020},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.orglett.0c03653},
number = {23},
pages = {9376--9380},
doi = {10.1021/acs.orglett.0c03653}
}
MLA
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MLA Copy
Liu, Junheng, et al. “Site-Selective Functionalization of 7-Azaindoles via Carbene Transfer and Isolation of N-Aromatic Zwitterions.” Organic Letters, vol. 22, no. 23, Nov. 2020, pp. 9376-9380. https://doi.org/10.1021/acs.orglett.0c03653.