Mass-Transfer Resistances in the Catalytic Hydrodechlorination of Polychlorobiphenyls. Experimental Results of 2-Chlorobiphenyl Hydrodechlorination in a Slurry Reactor and in a Rotating Basket Reactor
Publication type: Journal Article
Publication date: 2001-04-03
scimago Q1
wos Q2
SJR: 0.828
CiteScore: 6.7
Impact factor: 3.9
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Abstract
The hydrodechlorination of 2-chlorobiphenyl promoted by a commercial Ni−Mo catalyst has been investigated in a stirred batch reactor (T = 300 °C and P = 20 bar) in order to analyze the mass-transfer resistances which might influence the performance of an industrial reactor. Powdered (diameter ≅ 100 μm) and full size particles (cylinders diameter = 3 mm; length = 4.5 mm) catalysts have been used. In the second case, a rotating basket reactor has been set up. The results of the investigation indicate that external mass-transfer resistances are not relevant in the majority of the cases. When catalyst pellets are adopted, the diffusion in the catalyst porosity plays a significant role and values of the effectiveness factor in the range 0.05−0.12 have been calculated.
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Total citations:
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Citations from 2024:
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(12%)
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Schioppa E., Murena F., Gioia F. Mass-Transfer Resistances in the Catalytic Hydrodechlorination of Polychlorobiphenyls. Experimental Results of 2-Chlorobiphenyl Hydrodechlorination in a Slurry Reactor and in a Rotating Basket Reactor // Industrial & Engineering Chemistry Research. 2001. Vol. 40. No. 9. pp. 2011-2016.
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Schioppa E., Murena F., Gioia F. Mass-Transfer Resistances in the Catalytic Hydrodechlorination of Polychlorobiphenyls. Experimental Results of 2-Chlorobiphenyl Hydrodechlorination in a Slurry Reactor and in a Rotating Basket Reactor // Industrial & Engineering Chemistry Research. 2001. Vol. 40. No. 9. pp. 2011-2016.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ie000584d
UR - https://doi.org/10.1021/ie000584d
TI - Mass-Transfer Resistances in the Catalytic Hydrodechlorination of Polychlorobiphenyls. Experimental Results of 2-Chlorobiphenyl Hydrodechlorination in a Slurry Reactor and in a Rotating Basket Reactor
T2 - Industrial & Engineering Chemistry Research
AU - Schioppa, Emiddio
AU - Murena, Fabio
AU - Gioia, Francesco
PY - 2001
DA - 2001/04/03
PB - American Chemical Society (ACS)
SP - 2011-2016
IS - 9
VL - 40
SN - 0888-5885
SN - 1520-5045
ER -
Cite this
BibTex (up to 50 authors)
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@article{2001_Schioppa,
author = {Emiddio Schioppa and Fabio Murena and Francesco Gioia},
title = {Mass-Transfer Resistances in the Catalytic Hydrodechlorination of Polychlorobiphenyls. Experimental Results of 2-Chlorobiphenyl Hydrodechlorination in a Slurry Reactor and in a Rotating Basket Reactor},
journal = {Industrial & Engineering Chemistry Research},
year = {2001},
volume = {40},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ie000584d},
number = {9},
pages = {2011--2016},
doi = {10.1021/ie000584d}
}
Cite this
MLA
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Schioppa, Emiddio, et al. “Mass-Transfer Resistances in the Catalytic Hydrodechlorination of Polychlorobiphenyls. Experimental Results of 2-Chlorobiphenyl Hydrodechlorination in a Slurry Reactor and in a Rotating Basket Reactor.” Industrial & Engineering Chemistry Research, vol. 40, no. 9, Apr. 2001, pp. 2011-2016. https://doi.org/10.1021/ie000584d.