Enhanced Signal-to-Background Ratios in Voltammetric Measurements Made at Diamond Thin-Film Electrochemical Interfaces
Тип публикации: Journal Article
Дата публикации: 1996-07-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.358
CiteScore: 10.7
Impact factor: 7.3
ISSN: 00032700, 15206882, 21542686
PubMed ID:
21619292
Analytical Chemistry
Краткое описание
Large signal-to-background (S/B) ratios for the Fe(CN)63-/4- and IrCl62-/3- redox couples in KCl have been observed in cyclic voltammetric measurements made at a conductive diamond thin-film electrode without any conventional surface pretreatment. The S/B ratios were a factor of ∼16 and 8 larger at diamond than at freshly polished glassy carbon (GC) for Fe(CN)63-/4- and IrCl62-/3-, respectively. The polycrystalline diamond film, grown on a p-Si(100) substrate, possessed significant cubic {100} faceting, as evidenced by AFM images, and was of high quality, as indicated by Raman spectroscopy. The high degree of electrochemical activity without surface pretreatment, the enhanced S/B ratios, and the excellent response stability demonstrate that diamond might be an attractive new electrode material for electroanalysis.
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107
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107
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ГОСТ
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Strojek J. W. et al. Enhanced Signal-to-Background Ratios in Voltammetric Measurements Made at Diamond Thin-Film Electrochemical Interfaces // Analytical Chemistry. 1996. Vol. 68. No. 13. pp. 2031-2037.
ГОСТ со всеми авторами (до 50)
Скопировать
Strojek J. W. Enhanced Signal-to-Background Ratios in Voltammetric Measurements Made at Diamond Thin-Film Electrochemical Interfaces // Analytical Chemistry. 1996. Vol. 68. No. 13. pp. 2031-2037.
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RIS
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TY - JOUR
DO - 10.1021/ac9506847
UR - https://doi.org/10.1021/ac9506847
TI - Enhanced Signal-to-Background Ratios in Voltammetric Measurements Made at Diamond Thin-Film Electrochemical Interfaces
T2 - Analytical Chemistry
AU - Strojek, Jerzy W.
PY - 1996
DA - 1996/07/01
PB - American Chemical Society (ACS)
SP - 2031-2037
IS - 13
VL - 68
PMID - 21619292
SN - 0003-2700
SN - 1520-6882
SN - 2154-2686
ER -
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BibTex (до 50 авторов)
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@article{1996_Strojek,
author = {Jerzy W. Strojek},
title = {Enhanced Signal-to-Background Ratios in Voltammetric Measurements Made at Diamond Thin-Film Electrochemical Interfaces},
journal = {Analytical Chemistry},
year = {1996},
volume = {68},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ac9506847},
number = {13},
pages = {2031--2037},
doi = {10.1021/ac9506847}
}
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MLA
Скопировать
Strojek, Jerzy W., et al. “Enhanced Signal-to-Background Ratios in Voltammetric Measurements Made at Diamond Thin-Film Electrochemical Interfaces.” Analytical Chemistry, vol. 68, no. 13, Jul. 1996, pp. 2031-2037. https://doi.org/10.1021/ac9506847.
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