Influence of Substituents in the Aromatic Ring on the Strength of Halogen Bonding in Iodobenzene Derivatives
Тип публикации: Journal Article
Дата публикации: 2020-09-17
scimago Q2
wos Q1
БС1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Краткое описание
Halogen bonding properties of 3,4,5-triiodobenzoic acid (1, 2), 1,2,3-triiodobenzene (3), pentaiodobenzoic acid ethanol solvate (4), hexaiodobenzene (5a, 5b, 5c), 2,4-diiodoaniline (6), 4-iodoaniline (7), 2-iodoaniline (8), 2-iodophenol (9), 4-iodophenol (10), 3-iodophenol (11) and 2,4,6-triiodophenol (12) has been studied. The results suggested that substituents other than halogen in aromatic ring affect XB properties of iodine substituents in ortho-, meta- and para-positions. The effect depends on the electron-withdrawing/electron-donating properties of the substituent. Thus, electron-withdrawing substituents with negative mesomeric effect favor m-iodines to act as XB donors and o- and p-iodines to act as XB acceptors. By contrast, electron substituents with positive mesomeric effect favor o- and p-iodines to act as XB donors and m-iodines to act as XB acceptors.
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Chernysheva M. V. et al. Influence of Substituents in the Aromatic Ring on the Strength of Halogen Bonding in Iodobenzene Derivatives // Crystal Growth and Design. 2020. Vol. 20. No. 11. pp. 7197-7210.
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Chernysheva M. V., Bulatova M., Ding X., Haukka M. Influence of Substituents in the Aromatic Ring on the Strength of Halogen Bonding in Iodobenzene Derivatives // Crystal Growth and Design. 2020. Vol. 20. No. 11. pp. 7197-7210.
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TY - JOUR
DO - 10.1021/acs.cgd.0c00866
UR - https://doi.org/10.1021/acs.cgd.0c00866
TI - Influence of Substituents in the Aromatic Ring on the Strength of Halogen Bonding in Iodobenzene Derivatives
T2 - Crystal Growth and Design
AU - Chernysheva, Maria V
AU - Bulatova, Margarita
AU - Ding, Xin
AU - Haukka, Matti
PY - 2020
DA - 2020/09/17
PB - American Chemical Society (ACS)
SP - 7197-7210
IS - 11
VL - 20
SN - 1528-7483
SN - 1528-7505
ER -
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@article{2020_Chernysheva,
author = {Maria V Chernysheva and Margarita Bulatova and Xin Ding and Matti Haukka},
title = {Influence of Substituents in the Aromatic Ring on the Strength of Halogen Bonding in Iodobenzene Derivatives},
journal = {Crystal Growth and Design},
year = {2020},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.cgd.0c00866},
number = {11},
pages = {7197--7210},
doi = {10.1021/acs.cgd.0c00866}
}
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MLA
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Chernysheva, Maria V., et al. “Influence of Substituents in the Aromatic Ring on the Strength of Halogen Bonding in Iodobenzene Derivatives.” Crystal Growth and Design, vol. 20, no. 11, Sep. 2020, pp. 7197-7210. https://doi.org/10.1021/acs.cgd.0c00866.