Zn(II)/Cd(II) Terephthalate Coordination Polymers Incorporating Bi-, Tri-, and Tetratopic Phenylamine Derivatives: Crystal Structures and Photoluminescent Properties
1
Publication type: Journal Article
Publication date: 2016-04-21
scimago Q2
wos Q1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Using reticular chemistry allowed the design and construction of four novel Zn(II)/Cd(II) coordination polymers, {[Zn(BTPA)(TPA)]·H2O}n (1), {[Zn(TTPA)(TPA)]·H2O}n (2), {[Cd2(TTPA)2(TPA)2(DMF)]·2H2O}n (3), and {[Cd(TTPBDA)(TPA)]0.5·DMF·H2O}n (4). They were successfully synthesized from bi-, tri-, and tetratopic phenylamine derivatives (BTPA = bis(4-(1H-1,2,4-triazol-1-yl)phenyl)amine, TTPA = tris(4-(1H-1,2,4-triazol-1-yl)phenyl)amine, TTPBDA = N4,N4,N4′,N4′-tetrakis(4-(1H-1,2,4-triazol-1-yl)phenyl)-(1,1′-biphenyl)-4,4′-diamine) incorporating a linear terephthalic acid (H2TPA) ligand and Zn(II)/Cd(II) nitrate salts. These transparent crystals present gradually increasing dimensionality and complexity upon extension of the denticity of the phenylamine organic building blocks, as clearly supported by single-crystal X-ray analysis, infrared spectroscopy, elemental analysis, powder X-ray diffraction, and thermogravimetric analysis. Complex 1 shows two-dimensional (2D) threefold-interpenetrating layers (2D + 2D...
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Total citations:
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Citations from 2025:
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Shi Z. et al. Zn(II)/Cd(II) Terephthalate Coordination Polymers Incorporating Bi-, Tri-, and Tetratopic Phenylamine Derivatives: Crystal Structures and Photoluminescent Properties // Crystal Growth and Design. 2016. Vol. 16. No. 5. pp. 2747-2755.
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Shi Z., Pan Z., Jia H. L., Chen S., Qin L., Zheng H. Zn(II)/Cd(II) Terephthalate Coordination Polymers Incorporating Bi-, Tri-, and Tetratopic Phenylamine Derivatives: Crystal Structures and Photoluminescent Properties // Crystal Growth and Design. 2016. Vol. 16. No. 5. pp. 2747-2755.
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TY - JOUR
DO - 10.1021/acs.cgd.6b00056
UR - https://doi.org/10.1021/acs.cgd.6b00056
TI - Zn(II)/Cd(II) Terephthalate Coordination Polymers Incorporating Bi-, Tri-, and Tetratopic Phenylamine Derivatives: Crystal Structures and Photoluminescent Properties
T2 - Crystal Growth and Design
AU - Shi, Zhenzhen
AU - Pan, Zhaorui
AU - Jia, Hai Lang
AU - Chen, shuguang
AU - Qin, Ling
AU - Zheng, He-Gen
PY - 2016
DA - 2016/04/21
PB - American Chemical Society (ACS)
SP - 2747-2755
IS - 5
VL - 16
SN - 1528-7483
SN - 1528-7505
ER -
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@article{2016_Shi,
author = {Zhenzhen Shi and Zhaorui Pan and Hai Lang Jia and shuguang Chen and Ling Qin and He-Gen Zheng},
title = {Zn(II)/Cd(II) Terephthalate Coordination Polymers Incorporating Bi-, Tri-, and Tetratopic Phenylamine Derivatives: Crystal Structures and Photoluminescent Properties},
journal = {Crystal Growth and Design},
year = {2016},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.cgd.6b00056},
number = {5},
pages = {2747--2755},
doi = {10.1021/acs.cgd.6b00056}
}
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MLA
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Shi, Zhenzhen, et al. “Zn(II)/Cd(II) Terephthalate Coordination Polymers Incorporating Bi-, Tri-, and Tetratopic Phenylamine Derivatives: Crystal Structures and Photoluminescent Properties.” Crystal Growth and Design, vol. 16, no. 5, Apr. 2016, pp. 2747-2755. https://doi.org/10.1021/acs.cgd.6b00056.