Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate))
Vasili Miluykov
1
,
O.N. Kataeva
1, 2
,
Dmitry Krivolapov
1
,
V.I. Kovalenko
1
,
Y. Krupskaya
3
,
V. E. Kataev
3
,
B. Büchner
3, 4
,
Irena Senkovska
5
,
Publication type: Journal Article
Publication date: 2016-08-05
scimago Q2
wos Q1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
A flexible and hydrolytically stable metal–organic framework [Mn(H2O)2(Fc(PHOO)2)·2H2O]n has been synthesized using ferrocene-based ligand bearing phosphinic groups (Fc(PHOOH)2 = 1,1′-ferrocenediyl-bis(H-phosphinic acid)). In this compound manganese atoms are bound by phosphinate fragments to give infinite chains, and the latter are interconnected by ferrocene groups to form two-dimensional coordination polymer. The elimination of both coordinated and lattice water molecules during heating up to 150 °C produced the compound, which is nonporous for nitrogen, but can selectively adsorb water over methanol and other solvents at 298 K. The reversible structural transformation during adsorption/desorption of water is also reflected in a change of magnetic properties of the metal–organic framework.
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37
Total citations:
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Citations from 2024:
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GOST
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Shekurov R. P. et al. Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate)) // Crystal Growth and Design. 2016. Vol. 16. No. 9. pp. 5084-5090.
GOST all authors (up to 50)
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Shekurov R. P., Miluykov V., Kataeva O., Krivolapov D., Sinyashin O. G., Gerasimova T. I., Katsyuba S. A., Kovalenko V., Krupskaya Y., Kataev V. E., Büchner B., Senkovska I., Kaskel S. Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate)) // Crystal Growth and Design. 2016. Vol. 16. No. 9. pp. 5084-5090.
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RIS
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TY - JOUR
DO - 10.1021/acs.cgd.6b00681
UR - https://doi.org/10.1021/acs.cgd.6b00681
TI - Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate))
T2 - Crystal Growth and Design
AU - Shekurov, Ruslan P
AU - Miluykov, Vasili
AU - Kataeva, O.N.
AU - Krivolapov, Dmitry
AU - Sinyashin, Oleg G.
AU - Gerasimova, Tatiana I.
AU - Katsyuba, Sergey A.
AU - Kovalenko, V.I.
AU - Krupskaya, Y.
AU - Kataev, V. E.
AU - Büchner, B.
AU - Senkovska, Irena
AU - Kaskel, Stefan
PY - 2016
DA - 2016/08/05
PB - American Chemical Society (ACS)
SP - 5084-5090
IS - 9
VL - 16
SN - 1528-7483
SN - 1528-7505
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Shekurov,
author = {Ruslan P Shekurov and Vasili Miluykov and O.N. Kataeva and Dmitry Krivolapov and Oleg G. Sinyashin and Tatiana I. Gerasimova and Sergey A. Katsyuba and V.I. Kovalenko and Y. Krupskaya and V. E. Kataev and B. Büchner and Irena Senkovska and Stefan Kaskel},
title = {Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate))},
journal = {Crystal Growth and Design},
year = {2016},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.cgd.6b00681},
number = {9},
pages = {5084--5090},
doi = {10.1021/acs.cgd.6b00681}
}
Cite this
MLA
Copy
Shekurov, Ruslan P., et al. “Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate)).” Crystal Growth and Design, vol. 16, no. 9, Aug. 2016, pp. 5084-5090. https://doi.org/10.1021/acs.cgd.6b00681.
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