L -Alanine/Nickel-Induced Size Sorting of Lanthanide(III) Ions in 4f-4f′ Heterometallic Complexes
Stanislav I. Bezzubov
1, 2
,
Yury A. Belousov
3
,
Yuriy A Belousov
4
,
Alfiya A. Bilyalova
3, 4
,
Maria A Lavrova
3, 4
,
Irina S. Zharinova
3, 4
,
Yuri M. Kiselev
3, 4
,
Vladimir D. Dolzhenko
3, 4
3
Publication type: Journal Article
Publication date: 2017-02-10
scimago Q2
wos Q1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
A versatile approach to create a novel class of mixed-lanthanide compounds with predetermined locations of different lanthanides in cationic and anionic positions has been developed. Pure 4f–4f′ heterometallic complexes were constructed from two independent building blocks: the complex cation [Ln{Ni(ala)2}6]3+ (ala = l-alaninate), which can be formed by La3+, Ce3+, Pr3+, and Nd3+ exclusively, and the anion [Gd(NO3)3(OH)3(H2O)]3–. The compositions and structures of the complexes were studied by X-ray crystallography, energy-dispersive X-ray spectroscopy, and inductively coupled plasma mass spectrometry. The X-ray structural analysis showed the high rigidity of the l-alanine/Ni(II) supramolecular unit in the complex cations, which affected immediately its selectivity toward certain lanthanides.
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Total citations:
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GOST
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Bezzubov S. I. et al. L -Alanine/Nickel-Induced Size Sorting of Lanthanide(III) Ions in 4f-4f′ Heterometallic Complexes // Crystal Growth and Design. 2017. Vol. 17. No. 3. pp. 1166-1172.
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Bezzubov S. I., Churakov A. V., Belousov Y. A., Belousov Y. A., Bilyalova A. A., Lavrova M. A., Zharinova I. S., Kiselev Y. M., Dolzhenko V. D. L -Alanine/Nickel-Induced Size Sorting of Lanthanide(III) Ions in 4f-4f′ Heterometallic Complexes // Crystal Growth and Design. 2017. Vol. 17. No. 3. pp. 1166-1172.
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TY - JOUR
DO - 10.1021/acs.cgd.6b01563
UR - https://pubs.acs.org/doi/10.1021/acs.cgd.6b01563
TI - L -Alanine/Nickel-Induced Size Sorting of Lanthanide(III) Ions in 4f-4f′ Heterometallic Complexes
T2 - Crystal Growth and Design
AU - Bezzubov, Stanislav I.
AU - Churakov, Andrei V.
AU - Belousov, Yury A.
AU - Belousov, Yuriy A
AU - Bilyalova, Alfiya A.
AU - Lavrova, Maria A
AU - Zharinova, Irina S.
AU - Kiselev, Yuri M.
AU - Dolzhenko, Vladimir D.
PY - 2017
DA - 2017/02/10
PB - American Chemical Society (ACS)
SP - 1166-1172
IS - 3
VL - 17
SN - 1528-7483
SN - 1528-7505
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Bezzubov,
author = {Stanislav I. Bezzubov and Andrei V. Churakov and Yury A. Belousov and Yuriy A Belousov and Alfiya A. Bilyalova and Maria A Lavrova and Irina S. Zharinova and Yuri M. Kiselev and Vladimir D. Dolzhenko},
title = {L -Alanine/Nickel-Induced Size Sorting of Lanthanide(III) Ions in 4f-4f′ Heterometallic Complexes},
journal = {Crystal Growth and Design},
year = {2017},
volume = {17},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://pubs.acs.org/doi/10.1021/acs.cgd.6b01563},
number = {3},
pages = {1166--1172},
doi = {10.1021/acs.cgd.6b01563}
}
Cite this
MLA
Copy
Bezzubov, Stanislav I., et al. “L -Alanine/Nickel-Induced Size Sorting of Lanthanide(III) Ions in 4f-4f′ Heterometallic Complexes.” Crystal Growth and Design, vol. 17, no. 3, Feb. 2017, pp. 1166-1172. https://pubs.acs.org/doi/10.1021/acs.cgd.6b01563.