Role of I2 Molecules and Weak Interactions in Supramolecular Assembling of Pseudo-Three-Dimensional Hybrid Bismuth Polyiodides: Synthesis, Structure, and Optical Properties of Phenylenediammonium Polyiodobismuthate(III)
Tatiana A Shestimerova
1
,
Nikita A Golubev
1
,
Natallia A Yelavik
1
,
Mikhail A Bykov
1
,
Anastasia V. Grigorieva
2
,
Zheng Wei
3
,
Publication type: Journal Article
Publication date: 2018-03-20
scimago Q2
wos Q1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Phenylenediammonium polyiodobismuthate(III), [PDA(BiI4)2·I2] (PDA = phenylenediammonium, [NH3C6H4NH3]2+), represents a new hybrid halometallate synthesized in a form of black well-shaped crystals by a facile reaction in aqueous solution of HI containing dissolved I2. It crystallizes in triclinic space group P1 with the unit cell parameters a = 7.761(1) A, b = 9.259(1) A, c = 9.689(1) A, α = 95.68(3)°, β = 103.19(3)°, γ = 93.56(3)°, and Z = 1. Its crystal structure comprises three levels of organization discriminated by a type of chemical bonding. The first level is provided by covalently bonded [BiI6] octahedra linked into [BiI4]∞– one-dimensional anionic chains; the second level features secondary bonds between the chains and I2 bridging molecules, whereas the third level is specified by the weak hydrogen N–H···I bonds involving a diammonium cation and I···I intermolecular interactions that additionally link anionic chains. Altogether, these three interaction types ensure the formation of a complex pseu...
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Total citations:
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Citations from 2024:
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(11%)
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Shestimerova T. A. et al. Role of I2 Molecules and Weak Interactions in Supramolecular Assembling of Pseudo-Three-Dimensional Hybrid Bismuth Polyiodides: Synthesis, Structure, and Optical Properties of Phenylenediammonium Polyiodobismuthate(III) // Crystal Growth and Design. 2018. Vol. 18. No. 4. pp. 2572-2578.
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Shestimerova T. A., Golubev N. A., Yelavik N. A., Bykov M. A., Grigorieva A. V., Wei Z., Dikarev E. V., Shevelkov A. V. Role of I2 Molecules and Weak Interactions in Supramolecular Assembling of Pseudo-Three-Dimensional Hybrid Bismuth Polyiodides: Synthesis, Structure, and Optical Properties of Phenylenediammonium Polyiodobismuthate(III) // Crystal Growth and Design. 2018. Vol. 18. No. 4. pp. 2572-2578.
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TY - JOUR
DO - 10.1021/acs.cgd.8b00179
UR - https://doi.org/10.1021/acs.cgd.8b00179
TI - Role of I2 Molecules and Weak Interactions in Supramolecular Assembling of Pseudo-Three-Dimensional Hybrid Bismuth Polyiodides: Synthesis, Structure, and Optical Properties of Phenylenediammonium Polyiodobismuthate(III)
T2 - Crystal Growth and Design
AU - Shestimerova, Tatiana A
AU - Golubev, Nikita A
AU - Yelavik, Natallia A
AU - Bykov, Mikhail A
AU - Grigorieva, Anastasia V.
AU - Wei, Zheng
AU - Dikarev, Evgeny V.
AU - Shevelkov, Andrei V.
PY - 2018
DA - 2018/03/20
PB - American Chemical Society (ACS)
SP - 2572-2578
IS - 4
VL - 18
SN - 1528-7483
SN - 1528-7505
ER -
Cite this
BibTex (up to 50 authors)
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@article{2018_Shestimerova,
author = {Tatiana A Shestimerova and Nikita A Golubev and Natallia A Yelavik and Mikhail A Bykov and Anastasia V. Grigorieva and Zheng Wei and Evgeny V. Dikarev and Andrei V. Shevelkov},
title = {Role of I2 Molecules and Weak Interactions in Supramolecular Assembling of Pseudo-Three-Dimensional Hybrid Bismuth Polyiodides: Synthesis, Structure, and Optical Properties of Phenylenediammonium Polyiodobismuthate(III)},
journal = {Crystal Growth and Design},
year = {2018},
volume = {18},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.cgd.8b00179},
number = {4},
pages = {2572--2578},
doi = {10.1021/acs.cgd.8b00179}
}
Cite this
MLA
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Shestimerova, Tatiana A., et al. “Role of I2 Molecules and Weak Interactions in Supramolecular Assembling of Pseudo-Three-Dimensional Hybrid Bismuth Polyiodides: Synthesis, Structure, and Optical Properties of Phenylenediammonium Polyiodobismuthate(III).” Crystal Growth and Design, vol. 18, no. 4, Mar. 2018, pp. 2572-2578. https://doi.org/10.1021/acs.cgd.8b00179.
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