How Many Parameters Can Affect the Solid Form of Cocrystallization Products in Mechanochemical Reactions? A Case Study
Тип публикации: Journal Article
Дата публикации: 2018-11-16
scimago Q2
wos Q1
white level БС1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Краткое описание
Polymorphism of cocrystals is a fascinating research topic in the field of crystal engineering. For the often employed mechanochemical synthesis approach, the solvent polarity and the stoichiometric ratio of starting materials were previously confirmed as significant variables controlling the polymorphic outcomes. In this study, the 1:1 (THP-AH11) and 1:2 (THP-AH12) theophylline-acesulfame cocrystals were obtained by using mechanochemical method with different synthesis parameters. It was found that the solid form of the mechanochemical product can also be altered by grinding energy and forms of starting materials. All these effect factors are understandable from the point of view of energy mechanism, which modified either the energy barrier or the reaction pathway.
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Yuan Y. et al. How Many Parameters Can Affect the Solid Form of Cocrystallization Products in Mechanochemical Reactions? A Case Study // Crystal Growth and Design. 2018. Vol. 18. No. 12. pp. 7244-7247.
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Yuan Y., Wang L., Li D., DENG Z., ZHANG H. How Many Parameters Can Affect the Solid Form of Cocrystallization Products in Mechanochemical Reactions? A Case Study // Crystal Growth and Design. 2018. Vol. 18. No. 12. pp. 7244-7247.
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TY - JOUR
DO - 10.1021/acs.cgd.8b01320
UR - https://doi.org/10.1021/acs.cgd.8b01320
TI - How Many Parameters Can Affect the Solid Form of Cocrystallization Products in Mechanochemical Reactions? A Case Study
T2 - Crystal Growth and Design
AU - Yuan, Yue
AU - Wang, Lin
AU - Li, Duanxiu
AU - DENG, ZONGWU
AU - ZHANG, HAILU
PY - 2018
DA - 2018/11/16
PB - American Chemical Society (ACS)
SP - 7244-7247
IS - 12
VL - 18
SN - 1528-7483
SN - 1528-7505
ER -
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@article{2018_Yuan,
author = {Yue Yuan and Lin Wang and Duanxiu Li and ZONGWU DENG and HAILU ZHANG},
title = {How Many Parameters Can Affect the Solid Form of Cocrystallization Products in Mechanochemical Reactions? A Case Study},
journal = {Crystal Growth and Design},
year = {2018},
volume = {18},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.cgd.8b01320},
number = {12},
pages = {7244--7247},
doi = {10.1021/acs.cgd.8b01320}
}
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Yuan, Yue, et al. “How Many Parameters Can Affect the Solid Form of Cocrystallization Products in Mechanochemical Reactions? A Case Study.” Crystal Growth and Design, vol. 18, no. 12, Nov. 2018, pp. 7244-7247. https://doi.org/10.1021/acs.cgd.8b01320.
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