Chemically Understanding the Liquid-Phase Synthesis of Argyrodite Solid Electrolyte Li6PS5Cl with the Highest Ionic Conductivity for All-Solid-State Batteries
2
Next-Generation Energy Systems Group, Centre of Excellence ENSEMBLE3 sp. z o.o., Wolczynska 133, Warsaw 01-919, Poland
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Publication type: Journal Article
Publication date: 2023-03-10
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Solid electrolytes (SEs), which essentially act as both the electron separator and ion conductor, play an important role in all-solid-state lithium-ion batteries. Liquid-phase synthesis is one of the promising methods as the synthesis of SEs is easily scalable and consumes lower energy. However, due to the complexity of the SEs prepared by liquid-phase synthesis, many problems such as impurities arise, making the liquid electrolytes irreplaceable. This study examines and solves the question why Li3PO4 is produced as an impurity upon preparing Li6PS5Cl argyrodite by approaching the chemical factors. This is accomplished by replacing the hydroxide-based solvent with a thiol-based solvent through liquid-phase synthesis. As a result, the absence of Li3PO4 from the Li6PS5Cl SEs in this study resulted in Li6PS5Cl attaining the highest ionic conductivity value (>2 mS·cm–1) ever obtained through liquid-phase synthesis. Furthermore, the absence of Li3PO4 in the argyrodite SE could magnificently increase the cell's capacity with remarkable stability.
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23
Total citations:
23
Citations from 2024:
20
(86%)
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Indrawan R. F. et al. Chemically Understanding the Liquid-Phase Synthesis of Argyrodite Solid Electrolyte Li6PS5Cl with the Highest Ionic Conductivity for All-Solid-State Batteries // Chemistry of Materials. 2023. Vol. 35. No. 6. pp. 2549-2558.
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Indrawan R. F., GAMO H., Nagai A., Matsuda A. Chemically Understanding the Liquid-Phase Synthesis of Argyrodite Solid Electrolyte Li6PS5Cl with the Highest Ionic Conductivity for All-Solid-State Batteries // Chemistry of Materials. 2023. Vol. 35. No. 6. pp. 2549-2558.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.chemmater.2c03818
UR - https://pubs.acs.org/doi/10.1021/acs.chemmater.2c03818
TI - Chemically Understanding the Liquid-Phase Synthesis of Argyrodite Solid Electrolyte Li6PS5Cl with the Highest Ionic Conductivity for All-Solid-State Batteries
T2 - Chemistry of Materials
AU - Indrawan, Radian Febi
AU - GAMO, Hirotada
AU - Nagai, Atsushi
AU - Matsuda, Atsunori
PY - 2023
DA - 2023/03/10
PB - American Chemical Society (ACS)
SP - 2549-2558
IS - 6
VL - 35
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
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@article{2023_Indrawan,
author = {Radian Febi Indrawan and Hirotada GAMO and Atsushi Nagai and Atsunori Matsuda},
title = {Chemically Understanding the Liquid-Phase Synthesis of Argyrodite Solid Electrolyte Li6PS5Cl with the Highest Ionic Conductivity for All-Solid-State Batteries},
journal = {Chemistry of Materials},
year = {2023},
volume = {35},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://pubs.acs.org/doi/10.1021/acs.chemmater.2c03818},
number = {6},
pages = {2549--2558},
doi = {10.1021/acs.chemmater.2c03818}
}
Cite this
MLA
Copy
Indrawan, Radian Febi, et al. “Chemically Understanding the Liquid-Phase Synthesis of Argyrodite Solid Electrolyte Li6PS5Cl with the Highest Ionic Conductivity for All-Solid-State Batteries.” Chemistry of Materials, vol. 35, no. 6, Mar. 2023, pp. 2549-2558. https://pubs.acs.org/doi/10.1021/acs.chemmater.2c03818.