Layered Oxychlorides [PbBiO2]An+1BnO3n–1Cl2 (A = Pb/Bi, B = Fe/Ti): Intergrowth of the Hematophanite and Sillen Phases
M. Batuk
1
,
Dmitry Batuk
1
,
A. A. Tsirlin
2
,
Dmitry S Filimonov
3
,
Denis Sheptyakov
4
,
Matthias Frontzek
4
,
Joke Hadermann
1
,
Artem M. Abakumov
1, 3
Publication type: Journal Article
Publication date: 2015-04-14
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
New layered structures corresponding to the general formula [PbBiO2]An+1BnO3n–1Cl2 were prepared. Pb5BiFe3O10Cl2 (n = 3) and Pb5Bi2Fe4O13Cl2 (n = 4) are built as a stacking of truncated An+1BnO3n–1 perovskite blocks and α-PbO-type [A2O2]2+ (A = Pb, Bi) blocks combined with chlorine sheets. The alternation of these structural blocks can be represented as an intergrowth between the hematophanite and Sillen-type structural blocks. The crystal and magnetic structures of Pb5BiFe3O10Cl2 and Pb5Bi2Fe4O13Cl2 were investigated in the temperature range of 1.5–700 K using X-ray and neutron powder diffraction, transmission electron microscopy and 57Fe Mossbauer spectroscopy. Both compounds crystallize in the I4/mmm space group with the unit cell parameters a ≈ ap ≈ 3.92 A (a unit-cell parameter of the perovskite structure), c ≈ 43.0 A for the n = 3 member and c ≈ 53.5 A for the n = 4 member. Despite the large separation between the slabs containing the Fe3+ ions (nearly 14 A), long-range antiferromagnetic order sets ...
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Total citations:
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Citations from 2024:
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(11.76%)
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Batuk M. et al. Layered Oxychlorides [PbBiO2]An+1BnO3n–1Cl2 (A = Pb/Bi, B = Fe/Ti): Intergrowth of the Hematophanite and Sillen Phases // Chemistry of Materials. 2015. Vol. 27. No. 8. pp. 2946-2956.
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Batuk M., Batuk D., Tsirlin A. A., Filimonov D. S., Sheptyakov D., Frontzek M., Hadermann J., Abakumov A. M. Layered Oxychlorides [PbBiO2]An+1BnO3n–1Cl2 (A = Pb/Bi, B = Fe/Ti): Intergrowth of the Hematophanite and Sillen Phases // Chemistry of Materials. 2015. Vol. 27. No. 8. pp. 2946-2956.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.chemmater.5b00233
UR - https://doi.org/10.1021/acs.chemmater.5b00233
TI - Layered Oxychlorides [PbBiO2]An+1BnO3n–1Cl2 (A = Pb/Bi, B = Fe/Ti): Intergrowth of the Hematophanite and Sillen Phases
T2 - Chemistry of Materials
AU - Batuk, M.
AU - Batuk, Dmitry
AU - Tsirlin, A. A.
AU - Filimonov, Dmitry S
AU - Sheptyakov, Denis
AU - Frontzek, Matthias
AU - Hadermann, Joke
AU - Abakumov, Artem M.
PY - 2015
DA - 2015/04/14
PB - American Chemical Society (ACS)
SP - 2946-2956
IS - 8
VL - 27
SN - 0897-4756
SN - 1520-5002
ER -
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BibTex (up to 50 authors)
Copy
@article{2015_Batuk,
author = {M. Batuk and Dmitry Batuk and A. A. Tsirlin and Dmitry S Filimonov and Denis Sheptyakov and Matthias Frontzek and Joke Hadermann and Artem M. Abakumov},
title = {Layered Oxychlorides [PbBiO2]An+1BnO3n–1Cl2 (A = Pb/Bi, B = Fe/Ti): Intergrowth of the Hematophanite and Sillen Phases},
journal = {Chemistry of Materials},
year = {2015},
volume = {27},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.chemmater.5b00233},
number = {8},
pages = {2946--2956},
doi = {10.1021/acs.chemmater.5b00233}
}
Cite this
MLA
Copy
Batuk, M., et al. “Layered Oxychlorides [PbBiO2]An+1BnO3n–1Cl2 (A = Pb/Bi, B = Fe/Ti): Intergrowth of the Hematophanite and Sillen Phases.” Chemistry of Materials, vol. 27, no. 8, Apr. 2015, pp. 2946-2956. https://doi.org/10.1021/acs.chemmater.5b00233.
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