KEu(MoO4)2: Polymorphism, Structures, and Luminescent Properties
Vladimir Alexei Morozov
1, 2
,
A. V. Arakcheeva
3, 4
,
Philip Pattison
3, 5
,
Nicolas Gauquelin
2
,
J. Verbeeck
2
,
4
Phase Solutions
Ltd., CH-1012 Lausanne, Switzerland
|
Publication type: Journal Article
Publication date: 2015-08-13
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
In this paper, with the example of two different polymorphs of KEu(MoO4)2, the influence of the ordering of the A-cations on the luminescent properties in scheelite related compounds (A′,A″)n[(B′,B″)O4]m is investigated. The polymorphs were synthesized using a solid state method. The study confirmed the existence of only two polymorphic forms at annealing temperature range 923–1203 K and ambient pressure: a low temperature anorthic α-phase and a monoclinic high temperature β-phase with an incommensurately modulated structure. The structures of both polymorphs were solved using transmission electron microscopy and refined from synchrotron powder X-ray diffraction data. The monoclinic β-KEu(MoO4)2 has a (3+1)-dimensional incommensurately modulated structure (superspace group I2/b(αβ0)00, a = 5.52645(4) A, b = 5.28277(4) A, c = 11.73797(8) A, γ = 91.2189(4)o, q = 0.56821(2)a*–0.12388(3)b*), whereas the anorthic α-phase is (3+1)-dimensional commensurately modulated (superspace group I1(αβγ)0, a = 5.58727(22)...
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34
Total citations:
34
Citations from 2024:
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(20.59%)
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GOST
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Morozov V. A. et al. KEu(MoO4)2: Polymorphism, Structures, and Luminescent Properties // Chemistry of Materials. 2015. Vol. 27. No. 16. pp. 5519-5530.
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Morozov V. A., Arakcheeva A. V., Pattison P., Gauquelin N., Verbeeck J., Abakumov A. M., Hadermann J. KEu(MoO4)2: Polymorphism, Structures, and Luminescent Properties // Chemistry of Materials. 2015. Vol. 27. No. 16. pp. 5519-5530.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.chemmater.5b01622
UR - https://doi.org/10.1021/acs.chemmater.5b01622
TI - KEu(MoO4)2: Polymorphism, Structures, and Luminescent Properties
T2 - Chemistry of Materials
AU - Morozov, Vladimir Alexei
AU - Arakcheeva, A. V.
AU - Pattison, Philip
AU - Gauquelin, Nicolas
AU - Verbeeck, J.
AU - Abakumov, Artem M.
AU - Hadermann, Joke
PY - 2015
DA - 2015/08/13
PB - American Chemical Society (ACS)
SP - 5519-5530
IS - 16
VL - 27
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Morozov,
author = {Vladimir Alexei Morozov and A. V. Arakcheeva and Philip Pattison and Nicolas Gauquelin and J. Verbeeck and Artem M. Abakumov and Joke Hadermann},
title = {KEu(MoO4)2: Polymorphism, Structures, and Luminescent Properties},
journal = {Chemistry of Materials},
year = {2015},
volume = {27},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.chemmater.5b01622},
number = {16},
pages = {5519--5530},
doi = {10.1021/acs.chemmater.5b01622}
}
Cite this
MLA
Copy
Morozov, Vladimir Alexei, et al. “KEu(MoO4)2: Polymorphism, Structures, and Luminescent Properties.” Chemistry of Materials, vol. 27, no. 16, Aug. 2015, pp. 5519-5530. https://doi.org/10.1021/acs.chemmater.5b01622.
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