Bulk-Type All Solid-State Batteries with 5 V Class LiNi0.5Mn1.5O4 Cathode and Li10GeP2S12 Solid Electrolyte
Publication type: Journal Article
Publication date: 2016-04-12
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
All solid-state batteries are of key importance in the development of next-generation energy storage devices with high energy density. Herein, we report the fabrication and operation of bulk-type 5 V-class all solid-state batteries consisting of LiNi0.5Mn1.5O4 cathode, Li10GeP2S12 solid-electrolyte, and Li metal anode. The 1st discharge capacity is about 80 mAh g–1 with an average voltage of 4.3 V. The discharge capacity gradually decreases during the subsequent cycles. X-ray diffraction and electrochemical impedance spectroscopy measurements reveal that the capacity fading results from the growth of a resistive interfacial layer on the cathode composite. The development of suitable conductive additive and sulfide solid electrolyte materials is essential for the development of high-voltage all solid-state batteries.
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258
Total citations:
258
Citations from 2025:
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(13.18%)
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GOST
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Oh G. et al. Bulk-Type All Solid-State Batteries with 5 V Class LiNi0.5Mn1.5O4 Cathode and Li10GeP2S12 Solid Electrolyte // Chemistry of Materials. 2016. Vol. 28. No. 8. pp. 2634-2640.
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Oh G., Hirayama M., Ohmin K., Suzuki K., Kanno R. Bulk-Type All Solid-State Batteries with 5 V Class LiNi0.5Mn1.5O4 Cathode and Li10GeP2S12 Solid Electrolyte // Chemistry of Materials. 2016. Vol. 28. No. 8. pp. 2634-2640.
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RIS
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TY - JOUR
DO - 10.1021/acs.chemmater.5b04940
UR - https://doi.org/10.1021/acs.chemmater.5b04940
TI - Bulk-Type All Solid-State Batteries with 5 V Class LiNi0.5Mn1.5O4 Cathode and Li10GeP2S12 Solid Electrolyte
T2 - Chemistry of Materials
AU - Oh, Gwangseok
AU - Hirayama, Masaaki
AU - Ohmin, Kwon
AU - Suzuki, Kota
AU - Kanno, Ryoji
PY - 2016
DA - 2016/04/12
PB - American Chemical Society (ACS)
SP - 2634-2640
IS - 8
VL - 28
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Oh,
author = {Gwangseok Oh and Masaaki Hirayama and Kwon Ohmin and Kota Suzuki and Ryoji Kanno},
title = {Bulk-Type All Solid-State Batteries with 5 V Class LiNi0.5Mn1.5O4 Cathode and Li10GeP2S12 Solid Electrolyte},
journal = {Chemistry of Materials},
year = {2016},
volume = {28},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.chemmater.5b04940},
number = {8},
pages = {2634--2640},
doi = {10.1021/acs.chemmater.5b04940}
}
Cite this
MLA
Copy
Oh, Gwangseok, et al. “Bulk-Type All Solid-State Batteries with 5 V Class LiNi0.5Mn1.5O4 Cathode and Li10GeP2S12 Solid Electrolyte.” Chemistry of Materials, vol. 28, no. 8, Apr. 2016, pp. 2634-2640. https://doi.org/10.1021/acs.chemmater.5b04940.