Chemistry of Materials, volume 28, issue 16, pages 5905-5915
Structural Insights and 3D Diffusion Pathways within the Lithium Superionic Conductor Li10GeP2S12
Dominik A. Weber
1
,
A. Senyshyn
2
,
Kai S Weldert
1
,
Sebastian Wenzel
1
,
Wenbo Zhang
1
,
René Kaiser
1
,
Stefan Berendts
3
,
Jürgen Janek
1
,
Publication type: Journal Article
Publication date: 2016-08-10
Journal:
Chemistry of Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 8.6
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Inspired by the ongoing debate about the ion dynamics in the lithium superionic conductor Li10GeP2S12 (LGPS), we present neutron powder diffraction data in combination with analyses of differential bond valence and nuclear density maps to elucidate the underlying diffusion pathways in Li10GeP2S12. LGPS exhibits quasi-isotropic three-dimensional lithium diffusion pathways, which is a combination of one-dimensional diffusion channels crossing two diffusion planes. Furthermore, ultrasonic speeds of sound measurements are used to understand the lattice dynamics and obtain the Debye temperature of LGPS. Temperature dependent X-ray diffraction is performed in order to understand the local temperature-dependent behavior of the prevalent structural backbone, as well as the thermal stability of the material. At elevated temperatures, the superionic conducting Li10GeP2S12 phase partially decomposes into Li4P2S6, explaining the deterioration of the ionic conductivity upon heating.
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Weber D. A. et al. Structural Insights and 3D Diffusion Pathways within the Lithium Superionic Conductor Li10GeP2S12 // Chemistry of Materials. 2016. Vol. 28. No. 16. pp. 5905-5915.
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Weber D. A., Senyshyn A., Weldert K. S., Wenzel S., Zhang W., Kaiser R., Berendts S., Janek J., Zeier W. G. Structural Insights and 3D Diffusion Pathways within the Lithium Superionic Conductor Li10GeP2S12 // Chemistry of Materials. 2016. Vol. 28. No. 16. pp. 5905-5915.
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TY - JOUR
DO - 10.1021/acs.chemmater.6b02424
UR - https://doi.org/10.1021/acs.chemmater.6b02424
TI - Structural Insights and 3D Diffusion Pathways within the Lithium Superionic Conductor Li10GeP2S12
T2 - Chemistry of Materials
AU - Weldert, Kai S
AU - Wenzel, Sebastian
AU - Zhang, Wenbo
AU - Kaiser, René
AU - Berendts, Stefan
AU - Weber, Dominik A.
AU - Senyshyn, A.
AU - Janek, Jürgen
AU - Zeier, Wolfgang G.
PY - 2016
DA - 2016/08/10 00:00:00
PB - American Chemical Society (ACS)
SP - 5905-5915
IS - 16
VL - 28
SN - 0897-4756
SN - 1520-5002
ER -
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@article{2016_Weber,
author = {Kai S Weldert and Sebastian Wenzel and Wenbo Zhang and René Kaiser and Stefan Berendts and Dominik A. Weber and A. Senyshyn and Jürgen Janek and Wolfgang G. Zeier},
title = {Structural Insights and 3D Diffusion Pathways within the Lithium Superionic Conductor Li10GeP2S12},
journal = {Chemistry of Materials},
year = {2016},
volume = {28},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.chemmater.6b02424},
number = {16},
pages = {5905--5915},
doi = {10.1021/acs.chemmater.6b02424}
}
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Weber, Dominik A., et al. “Structural Insights and 3D Diffusion Pathways within the Lithium Superionic Conductor Li10GeP2S12.” Chemistry of Materials, vol. 28, no. 16, Aug. 2016, pp. 5905-5915. https://doi.org/10.1021/acs.chemmater.6b02424.