New Insight into the Formation of Hybrid Perovskite Nanowires via Structure Directing Adducts
Andrey Petrov
1
,
Norman Pellet
2
,
Ji-Youn Seo
2
,
Nikolai A Belich
1
,
D. P. Kovalev
3
,
Eugene Goodilin
1, 4
,
S. M. Zakeeruddin
2
,
Alexey Tarasov
1, 4
,
1
Publication type: Journal Article
Publication date: 2016-12-28
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
We report a facile preparation approach of MAPbBr3, MAPbCl3, or FAPbBr3 (where MA = CH3NH3+ and FA = CH(NH2)2+) perovskite nanowires via sequential synthesis of MAPbI3 and FAPbI3 nanowires with chemically controlled composition and morphologies followed by an exchange of halide anions. The nanowires formation sequence includes intermediate phases such as MAI-PbI2-DMF and FAI-PbI2-DMF (DMF = dimethylformamide) acting as structure directing agent. The 1D shape of the adduct is preserved during the conversion to perovskite. The adducts play the role of key precursors controlling the final product morphology. Systematic investigations of the observed phase transformations and morphology features on multiple length scales revealed the effectiveness of the suggested synthetic route utilizing an original pseudomorph formation mechanism of the 1D structures to produce partly oriented films and textured layers of the nanowires via only a few experimental steps.
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78
Total citations:
78
Citations from 2024:
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(15%)
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GOST
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Petrov A. et al. New Insight into the Formation of Hybrid Perovskite Nanowires via Structure Directing Adducts // Chemistry of Materials. 2016. Vol. 29. No. 2. pp. 587-594.
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Petrov A., Pellet N., Seo J., Belich N. A., Kovalev D. P., Shevelkov A. V., Goodilin E., Zakeeruddin S. M., Tarasov A., Gratzel M. New Insight into the Formation of Hybrid Perovskite Nanowires via Structure Directing Adducts // Chemistry of Materials. 2016. Vol. 29. No. 2. pp. 587-594.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.6b03965
UR - https://doi.org/10.1021/acs.chemmater.6b03965
TI - New Insight into the Formation of Hybrid Perovskite Nanowires via Structure Directing Adducts
T2 - Chemistry of Materials
AU - Petrov, Andrey
AU - Pellet, Norman
AU - Seo, Ji-Youn
AU - Belich, Nikolai A
AU - Kovalev, D. P.
AU - Shevelkov, Andrei V.
AU - Goodilin, Eugene
AU - Zakeeruddin, S. M.
AU - Tarasov, Alexey
AU - Gratzel, M.
PY - 2016
DA - 2016/12/28
PB - American Chemical Society (ACS)
SP - 587-594
IS - 2
VL - 29
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Petrov,
author = {Andrey Petrov and Norman Pellet and Ji-Youn Seo and Nikolai A Belich and D. P. Kovalev and Andrei V. Shevelkov and Eugene Goodilin and S. M. Zakeeruddin and Alexey Tarasov and M. Gratzel},
title = {New Insight into the Formation of Hybrid Perovskite Nanowires via Structure Directing Adducts},
journal = {Chemistry of Materials},
year = {2016},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.chemmater.6b03965},
number = {2},
pages = {587--594},
doi = {10.1021/acs.chemmater.6b03965}
}
Cite this
MLA
Copy
Petrov, Andrey, et al. “New Insight into the Formation of Hybrid Perovskite Nanowires via Structure Directing Adducts.” Chemistry of Materials, vol. 29, no. 2, Dec. 2016, pp. 587-594. https://doi.org/10.1021/acs.chemmater.6b03965.