Chemistry of Materials, volume 29, issue 2, pages 735-741
High-Pressure Synthesis of a Pentazolate Salt
Brad A. Steele
1
,
E. Stavrou
2
,
Jonathan Crowhurst
2
,
J. M. Zaug
2
,
V. Prakapenka
3
,
I.I. Oleynik
1
Publication type: Journal Article
Publication date: 2016-12-19
Journal:
Chemistry of Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 8.6
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
The pentazolates, the last all-nitrogen members of the azole series, have been notoriously elusive for the last hundred years despite enormous efforts to make these compounds in either gas or condensed phases. Here, we report a successful synthesis of a solid state compound consisting of isolated pentazolate anions N5–, which is achieved by compressing and laser heating cesium azide (CsN3) mixed with N2 cryogenic liquid in a diamond anvil cell. The experiment was guided by theory, which predicted the transformation of the mixture at high pressures to a new compound, cesium pentazolate salt (CsN5). Electron transfer from Cs atoms to N5 rings enables both aromaticity in the pentazolates as well as ionic bonding in the CsN5 crystal. This work provides critical insight into the role of extreme conditions in exploring unusual bonding routes that ultimately lead to the formation of novel high nitrogen content species.
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Steele B. A. et al. High-Pressure Synthesis of a Pentazolate Salt // Chemistry of Materials. 2016. Vol. 29. No. 2. pp. 735-741.
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Steele B. A., Stavrou E., Crowhurst J., Zaug J. M., Prakapenka V., Oleynik I. High-Pressure Synthesis of a Pentazolate Salt // Chemistry of Materials. 2016. Vol. 29. No. 2. pp. 735-741.
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TY - JOUR
DO - 10.1021/acs.chemmater.6b04538
UR - https://doi.org/10.1021/acs.chemmater.6b04538
TI - High-Pressure Synthesis of a Pentazolate Salt
T2 - Chemistry of Materials
AU - Oleynik, I.I.
AU - Steele, Brad A.
AU - Stavrou, E.
AU - Crowhurst, Jonathan
AU - Zaug, J. M.
AU - Prakapenka, V.
PY - 2016
DA - 2016/12/19 00:00:00
PB - American Chemical Society (ACS)
SP - 735-741
IS - 2
VL - 29
SN - 0897-4756
SN - 1520-5002
ER -
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@article{2016_Steele,
author = {I.I. Oleynik and Brad A. Steele and E. Stavrou and Jonathan Crowhurst and J. M. Zaug and V. Prakapenka},
title = {High-Pressure Synthesis of a Pentazolate Salt},
journal = {Chemistry of Materials},
year = {2016},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.chemmater.6b04538},
number = {2},
pages = {735--741},
doi = {10.1021/acs.chemmater.6b04538}
}
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MLA
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Steele, Brad A., et al. “High-Pressure Synthesis of a Pentazolate Salt.” Chemistry of Materials, vol. 29, no. 2, Dec. 2016, pp. 735-741. https://doi.org/10.1021/acs.chemmater.6b04538.