Mechanism of Zn Insertion into Nanostructured δ-MnO2: A Nonaqueous Rechargeable Zn Metal Battery
Sang-Don Han
1
,
Soojeong Kim
1
,
Dongguo Li
1
,
V. Petkov
2
,
Patrick J Phillips
1, 3
,
Hong Wang
1
,
Jae Jin Kim
1
,
Karen L. More
4
,
Baris Key
1
,
Robert F Klie
1, 3
,
Vojislav Stamenkovic
1
,
Timothy Fister
1
,
Nenad M. Markovic
1
,
Anthony K. Burrell
1
,
Sanja Tepavcevic
1
,
Publication type: Journal Article
Publication date: 2017-05-19
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Unlike the more established lithium-ion based energy storage chemistries, the complex intercalation chemistry of multivalent cations in a host lattice is not well understood, especially the relationship between the intercalating species solution chemistry and the prevalence and type of side reactions. Among multivalent metals, a promising model system can be based on nonaqueous Zn2+ ion chemistry. Several examples of these systems support the use of a Zn metal anode, and reversible intercalation cathodes have been reported. This study utilizes a combination of analytical tools to probe the chemistry of a nanostructured δ-MnO2 cathode in association with a nonaqueous acetonitrile–Zn(TFSI)2 electrolyte and a Zn metal anode. As many of the issues related to understanding a multivalent battery relate to the electrolyte–electrode interface, the high surface area of a nanostructured cathode provides a significant interface between the electrolyte and cathode host that maximizes the spectroscopic signal of any s...
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252
Total citations:
252
Citations from 2024:
40
(15%)
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MLA
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GOST
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Han S. et al. Mechanism of Zn Insertion into Nanostructured δ-MnO2: A Nonaqueous Rechargeable Zn Metal Battery // Chemistry of Materials. 2017. Vol. 29. No. 11. pp. 4874-4884.
GOST all authors (up to 50)
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Han S., Kim S., Li D., Petkov V., Phillips P. J., Wang H., Kim J. J., More K. L., Key B., Klie R. F., Stamenkovic V., Fister T., Markovic N. M., Burrell A. K., Tepavcevic S., Vaughey J. T. Mechanism of Zn Insertion into Nanostructured δ-MnO2: A Nonaqueous Rechargeable Zn Metal Battery // Chemistry of Materials. 2017. Vol. 29. No. 11. pp. 4874-4884.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.7b00852
UR - https://doi.org/10.1021/acs.chemmater.7b00852
TI - Mechanism of Zn Insertion into Nanostructured δ-MnO2: A Nonaqueous Rechargeable Zn Metal Battery
T2 - Chemistry of Materials
AU - Han, Sang-Don
AU - Kim, Soojeong
AU - Li, Dongguo
AU - Petkov, V.
AU - Phillips, Patrick J
AU - Wang, Hong
AU - Kim, Jae Jin
AU - More, Karen L.
AU - Key, Baris
AU - Klie, Robert F
AU - Stamenkovic, Vojislav
AU - Fister, Timothy
AU - Markovic, Nenad M.
AU - Burrell, Anthony K.
AU - Tepavcevic, Sanja
AU - Vaughey, John T
PY - 2017
DA - 2017/05/19
PB - American Chemical Society (ACS)
SP - 4874-4884
IS - 11
VL - 29
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Han,
author = {Sang-Don Han and Soojeong Kim and Dongguo Li and V. Petkov and Patrick J Phillips and Hong Wang and Jae Jin Kim and Karen L. More and Baris Key and Robert F Klie and Vojislav Stamenkovic and Timothy Fister and Nenad M. Markovic and Anthony K. Burrell and Sanja Tepavcevic and John T Vaughey},
title = {Mechanism of Zn Insertion into Nanostructured δ-MnO2: A Nonaqueous Rechargeable Zn Metal Battery},
journal = {Chemistry of Materials},
year = {2017},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.chemmater.7b00852},
number = {11},
pages = {4874--4884},
doi = {10.1021/acs.chemmater.7b00852}
}
Cite this
MLA
Copy
Han, Sang-Don, et al. “Mechanism of Zn Insertion into Nanostructured δ-MnO2: A Nonaqueous Rechargeable Zn Metal Battery.” Chemistry of Materials, vol. 29, no. 11, May. 2017, pp. 4874-4884. https://doi.org/10.1021/acs.chemmater.7b00852.