New 4V-Class and Zero-Strain Cathode Material for Na-Ion Batteries
Publication type: Journal Article
Publication date: 2017-09-01
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Here, we introduce Na3V(PO3)3N as a novel 4V-class and zero-strain cathode material for Na-ion batteries. Structural analysis based on a combination of neutron and X-ray diffraction (XRD) reveals that the Na3V(PO3)3N crystal contains three-dimensional channels that are suitable for facile Na diffusion. The Na (de)intercalation is observed to occur at ∼4 V vs Na/Na+ in the Na cell via the V3+/V4+ redox reaction with ∼67% retention of the initial capacity after over 3000 cycles. The remarkable cycle stability is attributed to the near-zero volume change (∼0.24%) and unique centrosymmetric distortion that occurs during a cycle despite the large ionic size of Na ions for (de)intercalation, as demonstrated by ex situ XRD analysis and first-principles calculations. We also demonstrate that the Na3V(PO3)3N electrode can display outstanding power capability with ∼84% of the theoretical capacity retained at 10C, even though the particle sizes are on the micrometer scale (>5 μm), which is attributed to its intrinsi...
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67
Total citations:
67
Citations from 2024:
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(13%)
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GOST
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Kim J. et al. New 4V-Class and Zero-Strain Cathode Material for Na-Ion Batteries // Chemistry of Materials. 2017. Vol. 29. No. 18. pp. 7826-7832.
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Kim J., Yoon G., Kim H., Lee S., Kang K. New 4V-Class and Zero-Strain Cathode Material for Na-Ion Batteries // Chemistry of Materials. 2017. Vol. 29. No. 18. pp. 7826-7832.
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TY - JOUR
DO - 10.1021/acs.chemmater.7b02477
UR - https://doi.org/10.1021/acs.chemmater.7b02477
TI - New 4V-Class and Zero-Strain Cathode Material for Na-Ion Batteries
T2 - Chemistry of Materials
AU - Kim, Jongsoon
AU - Yoon, Gabin
AU - Kim, H.S.
AU - Lee, Seongsu
AU - Kang, Kisuk
PY - 2017
DA - 2017/09/01
PB - American Chemical Society (ACS)
SP - 7826-7832
IS - 18
VL - 29
SN - 0897-4756
SN - 1520-5002
ER -
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BibTex (up to 50 authors)
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@article{2017_Kim,
author = {Jongsoon Kim and Gabin Yoon and H.S. Kim and Seongsu Lee and Kisuk Kang},
title = {New 4V-Class and Zero-Strain Cathode Material for Na-Ion Batteries},
journal = {Chemistry of Materials},
year = {2017},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.chemmater.7b02477},
number = {18},
pages = {7826--7832},
doi = {10.1021/acs.chemmater.7b02477}
}
Cite this
MLA
Copy
Kim, Jongsoon, et al. “New 4V-Class and Zero-Strain Cathode Material for Na-Ion Batteries.” Chemistry of Materials, vol. 29, no. 18, Sep. 2017, pp. 7826-7832. https://doi.org/10.1021/acs.chemmater.7b02477.
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