Synthesis of Li-Rich NMC: A Comprehensive Study
Vanessa Pimenta
1
,
Dmitry Batuk
1, 2
,
Domitille Giaume
4, 5
,
Sophie Cassaignon
5, 6
,
Dominique Larcher
5, 7
,
Jean-Marie Tarascon
1, 5, 8
4
Publication type: Journal Article
Publication date: 2017-11-17
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Li-rich NMC are considered nowadays as one of the most promising candidates for high energy density cathodes. One significant challenge is nested in adjusting their synthesis conditions to reach optimum electrochemical performance, but no consensus has been reached yet on the ideal synthesis protocol. Herein, we revisited the elaboration of Li-rich NMC electrodes by focusing on the science involved through each synthesis steps using carbonate Ni0.1625Mn0.675Co0.1625CO3 precursor coprecipitation combined with solid state synthesis. We demonstrated the effect of precursor’s concentration on the kinetics of the precipitation reaction and provided clues to obtain spherically agglomerated NMC carbonates of different sizes. Moreover, we highlighted the strong impact of the Li2CO3/NMC carbonate ratio on the morphology and particles size of Li-rich NMC and subsequently on their electrochemical performance. Ratio of 1.35 was found to reproducibly give the best performance with namely a first discharge capacity of ...
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136
Total citations:
136
Citations from 2024:
32
(23.52%)
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GOST
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Pimenta V. et al. Synthesis of Li-Rich NMC: A Comprehensive Study // Chemistry of Materials. 2017. Vol. 29. No. 23. pp. 9923-9936.
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Pimenta V., Mariyappan S., Batuk D., Abakumov A. M., Giaume D., Cassaignon S., Larcher D., Tarascon J. Synthesis of Li-Rich NMC: A Comprehensive Study // Chemistry of Materials. 2017. Vol. 29. No. 23. pp. 9923-9936.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.7b03230
UR - https://doi.org/10.1021/acs.chemmater.7b03230
TI - Synthesis of Li-Rich NMC: A Comprehensive Study
T2 - Chemistry of Materials
AU - Pimenta, Vanessa
AU - Mariyappan, Sathiya
AU - Batuk, Dmitry
AU - Abakumov, Artem M.
AU - Giaume, Domitille
AU - Cassaignon, Sophie
AU - Larcher, Dominique
AU - Tarascon, Jean-Marie
PY - 2017
DA - 2017/11/17
PB - American Chemical Society (ACS)
SP - 9923-9936
IS - 23
VL - 29
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Pimenta,
author = {Vanessa Pimenta and Sathiya Mariyappan and Dmitry Batuk and Artem M. Abakumov and Domitille Giaume and Sophie Cassaignon and Dominique Larcher and Jean-Marie Tarascon},
title = {Synthesis of Li-Rich NMC: A Comprehensive Study},
journal = {Chemistry of Materials},
year = {2017},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.chemmater.7b03230},
number = {23},
pages = {9923--9936},
doi = {10.1021/acs.chemmater.7b03230}
}
Cite this
MLA
Copy
Pimenta, Vanessa, et al. “Synthesis of Li-Rich NMC: A Comprehensive Study.” Chemistry of Materials, vol. 29, no. 23, Nov. 2017, pp. 9923-9936. https://doi.org/10.1021/acs.chemmater.7b03230.