New Solid Electrolyte Na9Al(MoO4)6: Structure and Na+ Ion Conductivity
Anton L Buzlukov
3
,
Irina Yu Arapova
3
,
Yana V Baklanova
4
,
Tatiana A. Denisova
4
,
N. A. Medvedeva
4
,
Michel Bardet
5, 6
,
Joke Hadermann
7
,
Elena Khaikina
1, 8
6
CEA, INAC, MEM/LRM, F-38054 Grenoble, France
|
Publication type: Journal Article
Publication date: 2017-10-06
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Solid electrolytes are important materials with a wide range of technological applications. This work reports the crystal structure and electrical properties of a new solid electrolyte Na9Al(MoO4)6. The monoclinic Na9Al(MoO4)6 consists of isolated polyhedral [Al(MoO4)6]9– clusters composed of a central AlO6 octahedron sharing vertices with six MoO4 tetrahedra to form a three-dimensional framework. The AlO6 octahedron also shares edges with one Na1O6 octahedron and two Na2O6 octahedra. Na3–Na5 atoms are located in the framework cavities. The structure is related to that of sodium ion conductor II-Na3Fe2(AsO4)3. High-temperature conductivity measurements revealed that the conductivity (σ) of Na9Al(MoO4)6 at 803 K equals 1.63 × 10–2 S cm–1. The temperature behavior of the 23Na and 27Al nuclear magnetic resonance spectra and the spin-lattice relaxation rates of the 23Na nuclei indicate the presence of fast Na+ ion diffusion in the studied compound. At T<490 K, diffusion occurs by means of Na+ ion jumps exclus...
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37
Total citations:
37
Citations from 2024:
8
(21%)
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MLA
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GOST
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Savina A. A. et al. New Solid Electrolyte Na9Al(MoO4)6: Structure and Na+ Ion Conductivity // Chemistry of Materials. 2017. Vol. 29. No. 20. pp. 8901-8913.
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Savina A. A., Morozov V. A., Buzlukov A. L., Arapova I. Yu., Stefanovich S., Baklanova Y. V., Denisova T. A., Medvedeva N. A., Bardet M., Hadermann J., Lazoryak B. I., Khaikina E. New Solid Electrolyte Na9Al(MoO4)6: Structure and Na+ Ion Conductivity // Chemistry of Materials. 2017. Vol. 29. No. 20. pp. 8901-8913.
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RIS
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TY - JOUR
DO - 10.1021/acs.chemmater.7b03989
UR - https://doi.org/10.1021/acs.chemmater.7b03989
TI - New Solid Electrolyte Na9Al(MoO4)6: Structure and Na+ Ion Conductivity
T2 - Chemistry of Materials
AU - Savina, Aleksandra A.
AU - Morozov, Vladimir Alexei
AU - Buzlukov, Anton L
AU - Arapova, Irina Yu
AU - Stefanovich, Sergey
AU - Baklanova, Yana V
AU - Denisova, Tatiana A.
AU - Medvedeva, N. A.
AU - Bardet, Michel
AU - Hadermann, Joke
AU - Lazoryak, Bogdan I.
AU - Khaikina, Elena
PY - 2017
DA - 2017/10/06
PB - American Chemical Society (ACS)
SP - 8901-8913
IS - 20
VL - 29
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Savina,
author = {Aleksandra A. Savina and Vladimir Alexei Morozov and Anton L Buzlukov and Irina Yu Arapova and Sergey Stefanovich and Yana V Baklanova and Tatiana A. Denisova and N. A. Medvedeva and Michel Bardet and Joke Hadermann and Bogdan I. Lazoryak and Elena Khaikina},
title = {New Solid Electrolyte Na9Al(MoO4)6: Structure and Na+ Ion Conductivity},
journal = {Chemistry of Materials},
year = {2017},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.chemmater.7b03989},
number = {20},
pages = {8901--8913},
doi = {10.1021/acs.chemmater.7b03989}
}
Cite this
MLA
Copy
Savina, Aleksandra A., et al. “New Solid Electrolyte Na9Al(MoO4)6: Structure and Na+ Ion Conductivity.” Chemistry of Materials, vol. 29, no. 20, Oct. 2017, pp. 8901-8913. https://doi.org/10.1021/acs.chemmater.7b03989.
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