том 30 издание 3 страницы 990-997

Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis

Тип публикацииJournal Article
Дата публикации2018-01-22
scimago Q1
wos Q1
БС1
SJR2.065
CiteScore12.0
Impact factor7.0
ISSN08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Краткое описание
Crystalline Li7P3S11 is a promising solid electrolyte for all solid-state lithium/lithium ion batteries. A controllable liquid phase synthesis of Li7P3S11 is more desirable than conventional mechanochemical synthesis, but recent attempts suffer from reduced ionic conductivities. Here we elucidate the mechanism of formation of crystalline Li7P3S11 synthesized in the liquid phase [acetonitrile (ACN)]. We conclude that crystalline Li7P3S11 forms through a two-step reaction: (1) formation of solid Li3PS4·ACN and amorphous “Li2S·P2S5” phases in the liquid phase and (2) solid-state conversion of the two phases. The implication of this two-step reaction mechanism for morphology control and the transport properties of liquid phase synthesized Li7P3S11 is identified and discussed.
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ГОСТ |
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Wang Y. et al. Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis // Chemistry of Materials. 2018. Vol. 30. No. 3. pp. 990-997.
ГОСТ со всеми авторами (до 50) Скопировать
Wang Y., Lu D., Bowden M. E., El-Khoury P. Z., Han K. S., Deng Z., Xiao J., Zhang J., Liu J. Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis // Chemistry of Materials. 2018. Vol. 30. No. 3. pp. 990-997.
RIS |
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TY - JOUR
DO - 10.1021/acs.chemmater.7b04842
UR - https://doi.org/10.1021/acs.chemmater.7b04842
TI - Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis
T2 - Chemistry of Materials
AU - Wang, Yuxing
AU - Lu, Dongping
AU - Bowden, Mark E
AU - El-Khoury, Patrick Z.
AU - Han, Kee Sung
AU - Deng, Zhiqun
AU - Xiao, Jie
AU - Zhang, Ji-Guang
AU - Liu, Jun
PY - 2018
DA - 2018/01/22
PB - American Chemical Society (ACS)
SP - 990-997
IS - 3
VL - 30
SN - 0897-4756
SN - 1520-5002
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2018_Wang,
author = {Yuxing Wang and Dongping Lu and Mark E Bowden and Patrick Z. El-Khoury and Kee Sung Han and Zhiqun Deng and Jie Xiao and Ji-Guang Zhang and Jun Liu},
title = {Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis},
journal = {Chemistry of Materials},
year = {2018},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.chemmater.7b04842},
number = {3},
pages = {990--997},
doi = {10.1021/acs.chemmater.7b04842}
}
MLA
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Wang, Yuxing, et al. “Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis.” Chemistry of Materials, vol. 30, no. 3, Jan. 2018, pp. 990-997. https://doi.org/10.1021/acs.chemmater.7b04842.
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