Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis
Yuxing Wang
1
,
Dongping Lu
1
,
Mark E Bowden
2
,
Kee Sung Han
2
,
Zhiqun Deng
1
,
Jie Xiao
1
,
Ji-Guang Zhang
1
,
Jun Liu
1
Publication type: Journal Article
Publication date: 2018-01-22
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Crystalline Li7P3S11 is a promising solid electrolyte for all solid-state lithium/lithium ion batteries. A controllable liquid phase synthesis of Li7P3S11 is more desirable than conventional mechanochemical synthesis, but recent attempts suffer from reduced ionic conductivities. Here we elucidate the mechanism of formation of crystalline Li7P3S11 synthesized in the liquid phase [acetonitrile (ACN)]. We conclude that crystalline Li7P3S11 forms through a two-step reaction: (1) formation of solid Li3PS4·ACN and amorphous “Li2S·P2S5” phases in the liquid phase and (2) solid-state conversion of the two phases. The implication of this two-step reaction mechanism for morphology control and the transport properties of liquid phase synthesized Li7P3S11 is identified and discussed.
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135
Total citations:
135
Citations from 2024:
20
(14%)
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GOST
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Wang Y. et al. Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis // Chemistry of Materials. 2018. Vol. 30. No. 3. pp. 990-997.
GOST all authors (up to 50)
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Wang Y., Lu D., Bowden M. E., El-Khoury P. Z., Han K. S., Deng Z., Xiao J., Zhang J., Liu J. Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis // Chemistry of Materials. 2018. Vol. 30. No. 3. pp. 990-997.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.7b04842
UR - https://doi.org/10.1021/acs.chemmater.7b04842
TI - Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis
T2 - Chemistry of Materials
AU - Wang, Yuxing
AU - Lu, Dongping
AU - Bowden, Mark E
AU - El-Khoury, Patrick Z.
AU - Han, Kee Sung
AU - Deng, Zhiqun
AU - Xiao, Jie
AU - Zhang, Ji-Guang
AU - Liu, Jun
PY - 2018
DA - 2018/01/22
PB - American Chemical Society (ACS)
SP - 990-997
IS - 3
VL - 30
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Wang,
author = {Yuxing Wang and Dongping Lu and Mark E Bowden and Patrick Z. El-Khoury and Kee Sung Han and Zhiqun Deng and Jie Xiao and Ji-Guang Zhang and Jun Liu},
title = {Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis},
journal = {Chemistry of Materials},
year = {2018},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.chemmater.7b04842},
number = {3},
pages = {990--997},
doi = {10.1021/acs.chemmater.7b04842}
}
Cite this
MLA
Copy
Wang, Yuxing, et al. “Mechanism of Formation of Li7P3S11 Solid Electrolytes through Liquid Phase Synthesis.” Chemistry of Materials, vol. 30, no. 3, Jan. 2018, pp. 990-997. https://doi.org/10.1021/acs.chemmater.7b04842.