Applicability of Molybdite as an Electrode Material in Calcium Batteries: A Structural Study of Layer-type CaxMoO3
Publication type: Journal Article
Publication date: 2018-08-20
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Calcium batteries could be an alternative to lithium analogues, but this technology is still in its infancy. It is previously known that layered-type molybdite (α-MoO3) can intercalate hydrated calcium ions in aqueous electrolyte, and this intercalation process increases the interlayer spacing. In this work, we have found that α-MoO3 is electrochemically active in calcium cell with nonaqueous electrolyte. The mechanism of intercalation has been explored by using XRD, Raman, and XPS. The layered structure of α-MoO3 is preserved upon electrochemical intercalation of unsolvated calcium, and the perovskite-type structure of CaMoO3 is not formed. The experimental length of the lattice parameter perpendicular to the slab increases from 13.85 to 14.07 A in the first stages of intercalation. This limited increase can be optimum for achieving good electrochemical cycling. The model for calcium intercalation in the interlayer space was optimized by theoretical calculations based on the density functional theory. Th...
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Total citations:
82
Citations from 2024:
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(24.4%)
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GOST
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Cabello M. et al. Applicability of Molybdite as an Electrode Material in Calcium Batteries: A Structural Study of Layer-type CaxMoO3 // Chemistry of Materials. 2018. Vol. 30. No. 17. pp. 5853-5861.
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Cabello M., Nacimiento F., Alcántara R., Lavela P., Pérez-Vicente C., Tirado J. L. Applicability of Molybdite as an Electrode Material in Calcium Batteries: A Structural Study of Layer-type CaxMoO3 // Chemistry of Materials. 2018. Vol. 30. No. 17. pp. 5853-5861.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.8b01116
UR - https://doi.org/10.1021/acs.chemmater.8b01116
TI - Applicability of Molybdite as an Electrode Material in Calcium Batteries: A Structural Study of Layer-type CaxMoO3
T2 - Chemistry of Materials
AU - Cabello, Marta
AU - Nacimiento, Francisco
AU - Alcántara, Ricardo
AU - Lavela, P.
AU - Pérez-Vicente, Carlos
AU - Tirado, José L.
PY - 2018
DA - 2018/08/20
PB - American Chemical Society (ACS)
SP - 5853-5861
IS - 17
VL - 30
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
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@article{2018_Cabello,
author = {Marta Cabello and Francisco Nacimiento and Ricardo Alcántara and P. Lavela and Carlos Pérez-Vicente and José L. Tirado},
title = {Applicability of Molybdite as an Electrode Material in Calcium Batteries: A Structural Study of Layer-type CaxMoO3},
journal = {Chemistry of Materials},
year = {2018},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.chemmater.8b01116},
number = {17},
pages = {5853--5861},
doi = {10.1021/acs.chemmater.8b01116}
}
Cite this
MLA
Copy
Cabello, Marta, et al. “Applicability of Molybdite as an Electrode Material in Calcium Batteries: A Structural Study of Layer-type CaxMoO3.” Chemistry of Materials, vol. 30, no. 17, Aug. 2018, pp. 5853-5861. https://doi.org/10.1021/acs.chemmater.8b01116.