Structural Characterization of Pristine and Defective [Zr12(μ3-O)8(μ3-OH)8(μ2-OH)6]18+ Double-Node Metal–Organic Framework and Predicted Applications for Single-Site Catalytic Hydrolysis of Sarin
Publication type: Journal Article
Publication date: 2018-06-14
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Periodic PBE-D3 and M06-L calculations predict the lowest-energy proton topology of a [Zr6(μ3-O)4(μ3-OH)4(μ2-OH)3]2 ZrIV–MOF (J. Am. Chem. Soc. 2017, 139, 7004–7011), which has a unique double-node structure, to be 73.4 and 64.2 kcal/mol more stable than that originally proposed. Mono- and bidefective Zr12 secondary building units derived from this topology and built by removing one and two bridging terphenyldicarboxylate linkers and saturating the remaining open ZrIV metal sites with hydroxyl and aqua groups, are predicted to exhibit higher reactivity for the hydrolysis of sarin nerve agent than other coordinatively unsaturated Zr6-based MOFs reported to date.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
6
7
8
|
|
|
Journal of Physical Chemistry C
8 publications, 18.6%
|
|
|
ACS applied materials & interfaces
4 publications, 9.3%
|
|
|
Chemical Communications
3 publications, 6.98%
|
|
|
ACS Catalysis
2 publications, 4.65%
|
|
|
Dalton Transactions
2 publications, 4.65%
|
|
|
Journal of Materials Chemistry A
2 publications, 4.65%
|
|
|
Chemistry of Materials
1 publication, 2.33%
|
|
|
Inorganic Chemistry
1 publication, 2.33%
|
|
|
Trends in Chemistry
1 publication, 2.33%
|
|
|
Microporous and Mesoporous Materials
1 publication, 2.33%
|
|
|
Coordination Chemistry Reviews
1 publication, 2.33%
|
|
|
Cell Reports Physical Science
1 publication, 2.33%
|
|
|
Angewandte Chemie - International Edition
1 publication, 2.33%
|
|
|
Angewandte Chemie
1 publication, 2.33%
|
|
|
AICHE Journal
1 publication, 2.33%
|
|
|
Science China Materials
1 publication, 2.33%
|
|
|
Journal of Physical Chemistry Letters
1 publication, 2.33%
|
|
|
Chemical Reviews
1 publication, 2.33%
|
|
|
CrystEngComm
1 publication, 2.33%
|
|
|
Industrial & Engineering Chemistry Research
1 publication, 2.33%
|
|
|
Crystal Growth and Design
1 publication, 2.33%
|
|
|
Physical Chemistry Chemical Physics
1 publication, 2.33%
|
|
|
Analytical Imaging Techniques for Soft Matter Characterization
1 publication, 2.33%
|
|
|
Small
1 publication, 2.33%
|
|
|
Journal of Materials Chemistry C
1 publication, 2.33%
|
|
|
Chemical Society Reviews
1 publication, 2.33%
|
|
|
Scientia Sinica Chimica
1 publication, 2.33%
|
|
|
1
2
3
4
5
6
7
8
|
Publishers
|
5
10
15
20
|
|
|
American Chemical Society (ACS)
20 publications, 46.51%
|
|
|
Royal Society of Chemistry (RSC)
11 publications, 25.58%
|
|
|
Elsevier
5 publications, 11.63%
|
|
|
Wiley
4 publications, 9.3%
|
|
|
Springer Nature
2 publications, 4.65%
|
|
|
Science in China Press
1 publication, 2.33%
|
|
|
5
10
15
20
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
43
Total citations:
43
Citations from 2024:
3
(6%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Momeni M., Cramer C. S. Structural Characterization of Pristine and Defective [Zr12(μ3-O)8(μ3-OH)8(μ2-OH)6]18+ Double-Node Metal–Organic Framework and Predicted Applications for Single-Site Catalytic Hydrolysis of Sarin // Chemistry of Materials. 2018. Vol. 30. No. 13. pp. 4432-4439.
GOST all authors (up to 50)
Copy
Momeni M., Cramer C. S. Structural Characterization of Pristine and Defective [Zr12(μ3-O)8(μ3-OH)8(μ2-OH)6]18+ Double-Node Metal–Organic Framework and Predicted Applications for Single-Site Catalytic Hydrolysis of Sarin // Chemistry of Materials. 2018. Vol. 30. No. 13. pp. 4432-4439.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.8b01913
UR - https://doi.org/10.1021/acs.chemmater.8b01913
TI - Structural Characterization of Pristine and Defective [Zr12(μ3-O)8(μ3-OH)8(μ2-OH)6]18+ Double-Node Metal–Organic Framework and Predicted Applications for Single-Site Catalytic Hydrolysis of Sarin
T2 - Chemistry of Materials
AU - Momeni, M.
AU - Cramer, Christopher S.
PY - 2018
DA - 2018/06/14
PB - American Chemical Society (ACS)
SP - 4432-4439
IS - 13
VL - 30
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Momeni,
author = {M. Momeni and Christopher S. Cramer},
title = {Structural Characterization of Pristine and Defective [Zr12(μ3-O)8(μ3-OH)8(μ2-OH)6]18+ Double-Node Metal–Organic Framework and Predicted Applications for Single-Site Catalytic Hydrolysis of Sarin},
journal = {Chemistry of Materials},
year = {2018},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.chemmater.8b01913},
number = {13},
pages = {4432--4439},
doi = {10.1021/acs.chemmater.8b01913}
}
Cite this
MLA
Copy
Momeni, M., and Christopher S. Cramer. “Structural Characterization of Pristine and Defective [Zr12(μ3-O)8(μ3-OH)8(μ2-OH)6]18+ Double-Node Metal–Organic Framework and Predicted Applications for Single-Site Catalytic Hydrolysis of Sarin.” Chemistry of Materials, vol. 30, no. 13, Jun. 2018, pp. 4432-4439. https://doi.org/10.1021/acs.chemmater.8b01913.
Profiles