Chemistry of Materials, volume 31, issue 11, pages 3984-3991
Structures and Properties of Oxygen-Substituted Li10SiP2S12–xOx Solid-State Electrolytes
Publication type: Journal Article
Publication date: 2019-05-15
Journal:
Chemistry of Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 8.6
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Li10SiP2S12 (LSiPS), which has an Li10GeP2S12 (LGPS)-type crystalline structure, was synthesized by solid-state reaction and then doped with oxygen to produce oxy-sulfide compositions of the general formula Li10SiP2S12–xOx (LSiPSO), where 0 ≤ x ≤ 1.75. The phase distribution and local structural units present in the LSiPSO materials were determined via a combination of powder X-ray diffraction and Raman, Fourier-transform infrared, and solid-state nuclear magnetic resonance (NMR) spectroscopies. At smaller amounts of O substitution for S, x < 1, in LSiPS, the structure of the LSiPSO phases became more uniform in the LGPS structure from smaller amounts of the impurity β-Li3PS4 and more of the oxygen-substituted LGPS-like structure. Consistent with this, the Li ion conductivity increases in proportion to the decrease in the amount of the β-Li3PS4 phase and the growth of the LGPS-like phase. The highest lithium ionic conductivity was found for x = 0.7 at 3.1 (±0.4) × 10–3 S/cm at 25 °C. However, for x ≥ 0.9,...
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Kim K. H., Martin S. W. Structures and Properties of Oxygen-Substituted Li10SiP2S12–xOx Solid-State Electrolytes // Chemistry of Materials. 2019. Vol. 31. No. 11. pp. 3984-3991.
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Kim K. H., Martin S. W. Structures and Properties of Oxygen-Substituted Li10SiP2S12–xOx Solid-State Electrolytes // Chemistry of Materials. 2019. Vol. 31. No. 11. pp. 3984-3991.
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TY - JOUR
DO - 10.1021/acs.chemmater.9b00505
UR - https://doi.org/10.1021/acs.chemmater.9b00505
TI - Structures and Properties of Oxygen-Substituted Li10SiP2S12–xOx Solid-State Electrolytes
T2 - Chemistry of Materials
AU - Kim, Kwang Hyun
AU - Martin, Steve W
PY - 2019
DA - 2019/05/15 00:00:00
PB - American Chemical Society (ACS)
SP - 3984-3991
IS - 11
VL - 31
SN - 0897-4756
SN - 1520-5002
ER -
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@article{2019_Kim,
author = {Kwang Hyun Kim and Steve W Martin},
title = {Structures and Properties of Oxygen-Substituted Li10SiP2S12–xOx Solid-State Electrolytes},
journal = {Chemistry of Materials},
year = {2019},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.chemmater.9b00505},
number = {11},
pages = {3984--3991},
doi = {10.1021/acs.chemmater.9b00505}
}
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Kim, Kwang Hyun, and Steve W Martin. “Structures and Properties of Oxygen-Substituted Li10SiP2S12–xOx Solid-State Electrolytes.” Chemistry of Materials, vol. 31, no. 11, May. 2019, pp. 3984-3991. https://doi.org/10.1021/acs.chemmater.9b00505.