Nickel(II) and Copper(II) Coordination Polymers Derived from 1,2,4,5-Tetraaminobenzene for Lithium-Ion Batteries
Roman R Kapaev
1, 2, 3
,
Selina Olthof
4
,
I. S. ZHIDKOV
5
,
E. Z. Kurmaev
5, 6
,
Ernst Z Kurmaev
5, 6
,
Klaus Meerholz
4
,
Pavel A. Troshin
1, 2
2
3
Publication type: Journal Article
Publication date: 2019-06-25
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Highly conductive electrochemically active materials are required for developing a new generation of ultrafast lithium-ion batteries (LIBs). Recently, a novel family of transition metal coordination polymers derived from arylamines exhibited conductivities of over 1 S cm–1. Low molecular weight analogues of these materials show rich and reversible electrochemical behavior. However, there are just very few reports on the application of such materials in LIBs. In this paper, linear nickel(II) and copper(II) coordination polymers derived from 1,2,4,5-tetraaminobenzene are reported and investigated as anode and cathode materials for LIBs. In the anode mode, both materials show ultrafast cycling behavior with impressive stability. Particularly, for the nickel-based material, a specific capacity of 83 mA h g–1 is reached at 20 A g–1 current density, and 79% of this capacity is retained after 20 000 cycles. Moreover, the copper-based polymer used as a cathode component shows a specific capacity of up to 262 mA h...
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59
Total citations:
59
Citations from 2024:
11
(18%)
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GOST
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Kapaev R. R. et al. Nickel(II) and Copper(II) Coordination Polymers Derived from 1,2,4,5-Tetraaminobenzene for Lithium-Ion Batteries // Chemistry of Materials. 2019. Vol. 31. No. 14. pp. 5197-5205.
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Kapaev R. R., Olthof S., ZHIDKOV I. S., Kurmaev E. Z., Kurmaev E. Z., Stevenson K. J., Meerholz K., Troshin P. A. Nickel(II) and Copper(II) Coordination Polymers Derived from 1,2,4,5-Tetraaminobenzene for Lithium-Ion Batteries // Chemistry of Materials. 2019. Vol. 31. No. 14. pp. 5197-5205.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.chemmater.9b01366
UR - https://pubs.acs.org/doi/10.1021/acs.chemmater.9b01366
TI - Nickel(II) and Copper(II) Coordination Polymers Derived from 1,2,4,5-Tetraaminobenzene for Lithium-Ion Batteries
T2 - Chemistry of Materials
AU - Kapaev, Roman R
AU - Olthof, Selina
AU - ZHIDKOV, I. S.
AU - Kurmaev, E. Z.
AU - Kurmaev, Ernst Z
AU - Stevenson, Keith J
AU - Meerholz, Klaus
AU - Troshin, Pavel A.
PY - 2019
DA - 2019/06/25
PB - American Chemical Society (ACS)
SP - 5197-5205
IS - 14
VL - 31
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Kapaev,
author = {Roman R Kapaev and Selina Olthof and I. S. ZHIDKOV and E. Z. Kurmaev and Ernst Z Kurmaev and Keith J Stevenson and Klaus Meerholz and Pavel A. Troshin},
title = {Nickel(II) and Copper(II) Coordination Polymers Derived from 1,2,4,5-Tetraaminobenzene for Lithium-Ion Batteries},
journal = {Chemistry of Materials},
year = {2019},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://pubs.acs.org/doi/10.1021/acs.chemmater.9b01366},
number = {14},
pages = {5197--5205},
doi = {10.1021/acs.chemmater.9b01366}
}
Cite this
MLA
Copy
Kapaev, Roman R., et al. “Nickel(II) and Copper(II) Coordination Polymers Derived from 1,2,4,5-Tetraaminobenzene for Lithium-Ion Batteries.” Chemistry of Materials, vol. 31, no. 14, Jun. 2019, pp. 5197-5205. https://pubs.acs.org/doi/10.1021/acs.chemmater.9b01366.